Gold Warning: You are not logged in. Your IP address will be publicly visible if you make any edits. If you log in or create an account, your edits will be attributed to your username, along with other benefits.Anti-spam check. Do not fill this in! {{Short description|Chemical element and metal}} {{about|the element}} {{redirect|Element 79|the anthology|Element 79 (anthology){{!}}''Element 79'' (anthology)}} {{pp-vandalism|small=yes}} {{pp-move}} {{Use dmy dates|date=March 2024}} {{infobox gold}} '''Gold''' is a [[chemical element]]; it has the [[chemical symbol|symbol]] '''Au''' (from the [[Latin]] word "''aurum''") and the [[atomic number]] 79. In its pure form, it is a [[brightness|bright]], slightly orange-yellow, dense, soft, [[malleable]], and [[ductile]] [[metal]]. Chemically, gold is a [[transition metal]], a [[group 11 element]], and one of the [[Noble metal|noble metals]]. It is one of the least [[reactivity (chemistry)|reactive]] chemical elements, being the second-lowest in the [[reactivity series]]. It is solid under [[standard temperature and pressure|standard conditions]]. Gold often occurs in [[free element]]al ([[native state (metallurgy)|native state]]), as [[gold nugget|nuggets]] or grains, in [[rock (geology)|rocks]], [[vein (geology)|veins]], and [[alluvial deposit]]s. It occurs in a [[solid solution]] series with the native element [[silver]] (as in [[electrum]]), naturally [[alloy]]ed with other metals like [[copper]] and [[palladium]], and [[mineral inclusion]]s such as within [[pyrite]]. Less commonly, it occurs in minerals as gold compounds, often with [[tellurium]] ([[gold telluride]]s). Gold is resistant to most acids, though it does dissolve in [[aqua regia]] (a mixture of [[nitric acid]] and [[hydrochloric acid]]), forming a soluble [[tetrachloroaurate]] [[anion]]. Gold is insoluble in nitric acid alone, which dissolves silver and [[base metal]]s, a property long used to [[refining (metallurgy)|refine]] gold and confirm the presence of gold in metallic substances, giving rise to the term '[[acid test (gold)|acid test]]'. Gold dissolves in [[alkaline]] solutions of [[cyanide]], which are used in [[gold cyanidation|mining]] and [[electroplating]]. Gold also dissolves in [[mercury (element)|mercury]], forming [[amalgam (chemistry)|amalgam]] alloys, and as the gold acts simply as a solute, this is not a [[chemical reaction]]. A relatively rare element,<ref>{{cite book |last=Duckenfield |first=Mark |publisher=Routledge |date=2016 |title=The Monetary History of Gold: A Documentary History, 1660–1999 |url=https://books.google.com/books?id=VeJmDAAAQBAJ&pg=PA4 |page=4 |quote=Its scarcity makes it a useful store of value; however, its relative rarity reduced its utility as a currency, especially for transactions in small denominations. |isbn=9781315476124}}</ref><ref>{{cite book |last=Pearce |first=Susan M. |publisher=Smithsonian Books |date=1993 |title=Museums, Objects, and Collections: A Cultural Study |url=https://books.google.com/books?id=M6aZBwAAQBAJ&pg=PT53 |page=53 |quote=Its scarcity makes it a useful store of value; however, its relative rarity reduced its utility as a currency, especially for transactions in small denominations. ... Rarity is, nevertheless, in itself a source of value, and so is the degree of difficulty which surrounds the winning of the raw material, especially if it is exotic and has to be brought some distance. Gold is, geologically, a relatively rare material on Earth and occurs only in specific places which are remote from most other places. |isbn=9781588345172}}</ref> gold is a [[precious metal]] that has been used for [[gold coin|coinage]], [[jewelry]], and other [[works of art]] throughout [[recorded history]]. In the past, a [[gold standard]] was often implemented as a [[monetary policy]]. Gold coins ceased to be minted as a circulating currency in the 1930s, and the world gold standard was abandoned for a [[fiat currency]] system after the [[Nixon shock]] measures of 1971. In 2020, the [[list of countries by gold production|world's largest]] gold producer was China, followed by Russia and Australia.<ref name="production">{{cite web |title=Gold Production & Mining Data by Country |date=7 June 2023 |url=https://www.gold.org/goldhub/data/gold-production-by-country}}</ref> {{as of|2020}}, a total of around 201,296 [[tonne]]s of gold exist above ground.<ref>{{cite web |title=Above-ground stocks |url=https://www.gold.org/goldhub/data/above-ground-stocks |publisher=gold.org |access-date=18 October 2021}}</ref> This is equal to a cube, with each side measuring roughly {{convert|21.7|m|ft|sp=us}}. The world's consumption of new gold produced is about 50% in jewelry, 40% in [[investment]]s, and 10% in [[Manufacturing|industry]].<ref name='oil-price.com-worlds-gold-consumption 2011'>{{cite news |last=Soos |first=Andy |title=Gold Mining Boom Increasing Mercury Pollution Risk |date=6 January 2011 |publisher=Oilprice.com |url=http://oilprice.com/Metals/Gold/Gold-Mining-Boom-Increasing-Mercury-Pollution-Risk.html |work=Advanced Media Solutions, Inc. |access-date=26 March 2011}}</ref> Gold's high malleability, ductility, resistance to corrosion and most other chemical reactions, and conductivity of electricity have led to its continued use in corrosion-resistant [[electrical connector]]s in all types of computerized devices (its chief industrial use). Gold is also used in [[infrared]] shielding, the production of [[colored glass]], [[gold leaf]]ing, and [[restorative dentistry|tooth restoration]]. Certain [[gold salts]] are still used as [[anti-inflammatory]] agents in medicine. == Characteristics == [[File:Au atomic wire.jpg|thumb|left|Gold can be drawn into a monatomic wire, and then stretched more before it breaks.<ref name="Kizuka-2008" />]] [[File:Small gold nugget 5mm dia and corresponding foil surface of half sq meter.jpg|thumb|left|A gold nugget of {{convert|5|mm|abbr=on}} in size can be hammered into a [[gold foil]] of about {{convert|0.5|m2|abbr=on}} in area.]] Gold is the most [[malleable]] of all metals. It can be drawn into a wire of single-atom width, and then stretched considerably before it breaks.<ref name="Kizuka-2008">{{cite journal |last=Kizuka |first=Tokushi |title=Atomic configuration and mechanical and electrical properties of stable gold wires of single-atom width |url=https://tsukuba.repo.nii.ac.jp/record/16027/files/PRB-77_15.pdf |archive-url=https://web.archive.org/web/20210716175414/https://tsukuba.repo.nii.ac.jp/record/16027/files/PRB-77_15.pdf |archive-date=16 July 2021 |url-status=live |journal=Physical Review B |volume=77 |issue=15 |pages=155401 |date=1 April 2008 |bibcode=2008PhRvB..77o5401K|issn=1098-0121 |doi=10.1103/PhysRevB.77.155401 |hdl-access=free |hdl=2241/99261}}</ref> Such nanowires distort via the formation, reorientation, and migration of [[dislocation]]s and [[Crystal twinning|crystal twins]] without noticeable hardening.<ref>{{cite journal |last1=Che Lah |first1=Nurul Akmal |last2=Trigueros |first2=Sonia |title=Synthesis and modelling of the mechanical properties of Ag, Au and Cu nanowires |journal=[[Science and Technology of Advanced Materials]] |volume=20 |issue=1 |pages=225–261 |year=2019 |bibcode=2019STAdM..20..225L |pmid=30956731 |pmc=6442207 |doi=10.1080/14686996.2019.1585145}}</ref> A single gram of gold can be beaten into a sheet of {{convert|1|m2}}, and an [[avoirdupois ounce]] into {{convert|300|sqft|disp=flip}}. Gold leaf can be beaten thin enough to become semi-transparent. The transmitted light appears greenish-blue because gold strongly reflects yellow and red.<ref>{{cite web |url=http://www.webexhibits.org/causesofcolor/9.html |title=Gold: causes of color |access-date=6 June 2009}}</ref> Such semi-transparent sheets also strongly reflect [[infrared]] light, making them useful as infrared (radiant heat) shields in the visors of heat-resistant suits and in sun visors for [[spacesuit]]s.<ref>{{cite book |title=Suiting up for space: the evolution of the space suit |last=Mallan |first=Lloyd |date=1971 |publisher=John Day Co. |isbn=978-0-381-98150-1 |page=216}}</ref> Gold is a good [[Conduction (heat)|conductor of heat]] and [[Electrical conductor|electricity]]. Gold has a density of 19.3 g/cm<sup>3</sup>, almost identical to that of [[tungsten]] at 19.25 g/cm<sup>3</sup>; as such, tungsten has been used in the [[counterfeiting]] of [[gold bar]]s, such as by plating a tungsten bar with gold.<ref name="popsci">{{cite magazine |last=Gray |first=Theo |title=How to Make Convincing Fake-Gold Bars |url=http://www.popsci.com/diy/article/2008-03/how-make-convincing-fake-gold-bars |magazine=[[Popular Science]] |date=14 March 2008 |access-date=18 June 2008}}</ref><ref>Willie, Jim (18 November 2009) "[http://www.kitco.com/ind/willie/nov182009.html Zinc Dimes, Tungsten Gold & Lost Respect] {{webarchive |url=https://web.archive.org/web/20111008050729/http://www.kitco.com/ind/willie/nov182009.html |date=8 October 2011}}". Kitco</ref><ref>{{cite web |url=http://news.coinupdate.com/largest-private-refinery-discovers-gold-plated-tungsten-bar-0171/ |title=Largest Private Refinery Discovers Gold-Plated Tungsten Bar | Coin Update |website=news.coinupdate.com}}</ref><ref>{{cite news |title=Austrians Seize False Gold Tied to London Bullion Theft |work=[[The New York Times]] |access-date=25 March 2012 |date=22 December 1983 |url=https://www.nytimes.com/1983/12/22/world/austrians-seize-false-gold-tied-to-london-bullion-theft.html}}</ref> By comparison, the density of [[lead]] is 11.34 g/cm<sup>3</sup>, and that of the densest element, [[osmium]], is {{val|22.588|0.015|u=g/cm<sup>3</sup>}}.<ref name="Densest">{{cite journal |last=Arblaster |first=J. W. |title=Osmium, the Densest Metal Known |journal=Platinum Metals Review |volume=39 |issue=4 |date=1995 |page=164 |doi=10.1595/003214095X394164164 |s2cid=267393021 |url=http://www.technology.matthey.com/pdf/pmr-v39-i4-164-164.pdf |access-date=14 October 2016 |archive-date=18 October 2016 |archive-url=https://web.archive.org/web/20161018195547/http://www.technology.matthey.com/pdf/pmr-v39-i4-164-164.pdf |url-status=dead }}</ref><!-- 10.1038/nchem.1479 from 2012 gives same value--> === Color === {{Main|Colored gold}} [[File:Ag-Au-Cu-colours-english.svg|thumb|left|Different colors of [[Silver|Ag]]–Au–[[Copper|Cu]] alloys]] Whereas most metals are gray or silvery white, gold is slightly reddish-yellow.<ref name="chem">{{cite book |title=Encyclopædia of Chemistry, Theoretical, Practical, and Analytical, as Applied to the Arts and Manufacturers: Glass-zinc |url=https://books.google.com/books?id=o-FYAAAAYAAJ&pg=PA70 |year=1880 |publisher=J.B. Lippincott & Company |pages=70–}}</ref> This color is determined by the frequency of [[plasma oscillation]]s among the metal's valence electrons, in the ultraviolet range for most metals but in the visible range for gold due to [[relativistic quantum chemistry|relativistic effects]] affecting the [[atomic orbital|orbitals]] around gold atoms.<ref>{{cite web |url=http://math.ucr.edu/home/baez/physics/Relativity/SR/gold_color.html |title=Relativity in Chemistry |publisher=Math.ucr.edu |access-date=5 April 2009}}</ref><ref>{{Cite journal |first1=Hubert |last1=Schmidbaur |first2=Stephanie |last2=Cronje |first3=Bratislav |last3=Djordjevic |first4=Oliver |last4=Schuster |journal=Chemical Physics |volume=311 |pages=151–161 |title=Understanding gold chemistry through relativity |doi=10.1016/j.chemphys.2004.09.023 |date=2005 |issue=1–2 |bibcode=2005CP....311..151S}}</ref> Similar effects impart a golden hue to metallic [[caesium]]. Common colored gold alloys include the distinctive eighteen-karat [[rose gold]] created by the addition of copper. Alloys containing [[palladium]] or [[nickel]] are also important in commercial jewelry as these produce white gold alloys. Fourteen-karat gold-copper alloy is nearly identical in color to certain [[bronze]] alloys, and both may be used to produce police and other [[badge]]s. Fourteen- and eighteen-karat gold alloys with silver alone appear greenish-yellow and are referred to as [[green gold]]. Blue gold can be made by alloying with [[iron]], and purple gold can be made by alloying with [[aluminium]]. Less commonly, addition of [[manganese]], [[indium]], and other elements can produce more unusual colors of gold for various applications.<ref name="utilisegold" /> [[Colloidal gold]], used by electron-microscopists, is red if the particles are small; larger particles of colloidal gold are blue.<ref>{{Cite book |url=https://books.google.com/books?id=MzT9eWxtmRgC&pg=PA180 |title=Electron Microscopy in Microbiology |date=1988 |publisher=Academic Press |isbn=978-0-08-086049-7}}</ref> === Isotopes === {{Main|Isotopes of gold}} Gold has only one stable [[isotope]], {{chem|197|Au}}, which is also its only naturally occurring isotope, so gold is both a [[Mononuclidic element|mononuclidic]] and [[monoisotopic element]]. Thirty-six [[radioisotopes]] have been synthesized, ranging in [[atomic mass]] from 169 to 205. The most stable of these is {{chem|195|Au}} with a [[half-life]] of 186.1 days. The least stable is {{chem|171|Au}}, which decays by [[proton emission]] with a half-life of 30 µs. Most of gold's radioisotopes with atomic masses below 197 decay by some combination of [[proton emission]], [[alpha decay|α decay]], and [[β+ decay|β<sup>+</sup> decay]]. The exceptions are {{chem|195|Au}}, which decays by electron capture, and {{chem|196|Au}}, which decays most often by electron capture (93%) with a minor [[β− decay|β<sup>−</sup> decay]] path (7%).<ref>{{cite web |url=http://www.nndc.bnl.gov/nudat2/ |website=National Nuclear Data Center |title=Nudat 2 |access-date=12 April 2012}}</ref> All of gold's radioisotopes with atomic masses above 197 decay by β<sup>−</sup> decay.<ref name="nubase">{{NUBASE 2003}}</ref> At least 32 [[nuclear isomer]]s have also been characterized, ranging in atomic mass from 170 to 200. Within that range, only {{chem|178|Au}}, {{chem|180|Au}}, {{chem|181|Au}}, {{chem|182|Au}}, and {{chem|188|Au}} do not have isomers. Gold's most stable isomer is {{chem|198m2|Au}} with a half-life of 2.27 days. Gold's least stable isomer is {{chem|177m2|Au}} with a half-life of only 7 ns. {{chem|184m1|Au}} has three decay paths: β<sup>+</sup> decay, [[isomeric transition]], and alpha decay. No other isomer or isotope of gold has three decay paths.<ref name="nubase" /> ==== Synthesis ==== {{see also|Synthesis of precious metals}} The possible production of gold from a more common element, such as [[lead]], has long been a subject of human inquiry, and the ancient and medieval discipline of [[alchemy]] often focused on it; however, the transmutation of the chemical elements did not become possible until the understanding of [[nuclear physics]] in the 20th century. The first synthesis of gold was conducted by Japanese physicist [[Hantaro Nagaoka]], who synthesized gold from [[mercury (element)|mercury]] in 1924 by neutron bombardment.<ref>{{Cite journal |last1=Miethe |first1=A. |title=Der Zerfall des Quecksilberatoms |doi=10.1007/BF01505547 |journal=Die Naturwissenschaften |volume=12 |issue=29 |pages=597–598 |year=1924 |bibcode=1924NW.....12..597M|s2cid=35613814 }}</ref> An American team, working without knowledge of Nagaoka's prior study, conducted the same experiment in 1941, achieving the same result and showing that the [[isotopes of gold]] produced by it were all [[radioactive]].<ref>{{cite journal |last1=Sherr |first1=R. |first2=K. T. |last2=Bainbridge |first3=H. H. |last3=Anderson |name-list-style=amp |title=Transmutation of Mercury by Fast Neutrons |date=1941 |journal=[[Physical Review]] |volume=60 |issue=7 |pages=473–479 |doi=10.1103/PhysRev.60.473 |bibcode=1941PhRv...60..473S}}</ref> In 1980, [[Glenn T. Seaborg|Glenn Seaborg]] transmuted several thousand atoms of bismuth into gold at the Lawrence Berkeley Laboratory.<ref>{{Cite journal|last1=Aleklett |first1=K.|last2=Morrissey |first2=D.|last3=Loveland |first3=W.|last4=McGaughey |first4=P.|last5=Seaborg |first5=G.|year=1981|title=Energy dependence of <sup>209</sup>Bi fragmentation in relativistic nuclear collisions|journal=[[Physical Review C]]|volume=23 |issue=3 |page=1044|bibcode=1981PhRvC..23.1044A|doi=10.1103/PhysRevC.23.1044}}</ref><ref>{{cite news |url=https://www.telegraph.co.uk/education/4791069/The-Philosophers-Stone.html |newspaper=[[The Daily Telegraph]] |first=Robert |last=Matthews |title=The Philosopher's Stone |date=2 December 2001 |access-date=22 September 2020 }}</ref> Gold can be manufactured in a nuclear reactor, but doing so is highly impractical and would cost far more than the value of the gold that is produced.<ref>{{cite book |last1=Shipman |first1=James |last2=Wilson |first2=Jerry D. |last3=Higgins |first3=Charles A. |title=An Introduction to Physical Science |date=2012 |publisher=Cengage Learning |isbn=9781133709497 |page=273 |edition=13th}}</ref> == Chemistry == {{Main|Gold compounds}} [[File:Gold(III) chloride solution.jpg|thumb|right|Gold(III) chloride solution in water]] Although gold is the most noble of the noble metals,<ref>{{cite journal |doi=10.1038/376238a0 |title=Why gold is the noblest of all the metals |date=1995 |last1=Hammer |first1=B. |last2=Norskov |first2=J. K. |journal=Nature |volume=376 |issue=6537 |pages=238–240 |bibcode=1995Natur.376..238H|s2cid=4334587 }}</ref><ref>{{cite journal |doi=10.1103/PhysRevB.6.4370 |title=Optical Constants of the Noble Metals |date=1972 |last1=Johnson |first1=P. B. |last2=Christy |first2=R. W. |journal=Physical Review B |volume=6 |issue=12 |pages=4370–4379 |bibcode=1972PhRvB...6.4370J}}</ref> it still forms many diverse compounds. The [[oxidation state]] of gold in its compounds ranges from −1 to +5, but Au(I) and Au(III) dominate its chemistry. Au(I), referred to as the aurous ion, is the most common oxidation state with soft [[ligand]]s such as [[thioether]]s, [[thiolate]]s, and [[organophosphine]]s. Au(I) compounds are typically linear. A good example is {{chem2|[[gold cyanidation|Au(CN)2(−)]]}}, which is the soluble form of gold encountered in mining. The binary [[gold halide]]s, such as [[gold(I) chloride|AuCl]], form zigzag polymeric chains, again featuring linear coordination at Au. Most [[Gold-containing drugs|drugs based on gold]] are Au(I) derivatives.<ref>{{cite journal |last=Shaw III |first=C. F. |title=Gold-Based Medicinal Agents |journal=Chemical Reviews |date=1999 |volume=99 |issue=9 |pages=2589–2600 |doi=10.1021/cr980431o |pmid=11749494}}</ref> Au(III) (referred to as auric) is a common oxidation state, and is illustrated by [[gold(III) chloride]], {{chem2|Au2Cl6}}. The gold atom centers in Au(III) complexes, like other d<sup>8</sup> compounds, are typically [[square planar]], with [[chemical bond]]s that have both [[covalent]] and [[ion]]ic character. [[Gold(I,III) chloride]] is also known, an example of a [[mixed-valence complex]]. Gold does not react with oxygen at any temperature<ref>{{cite web |url=http://chemwiki.ucdavis.edu/Core/Inorganic_Chemistry/Descriptive_Chemistry/Elements_Organized_by_Block/2_p-Block_Elements/Group_16%253A_The_Oxygen_Family/Chemistry_of_Oxygen |title=Chemistry of Oxygen |website=Chemwiki [[UC Davis]]|access-date=1 May 2016 |date=2 October 2013}}</ref> and, up to 100 °C, is resistant to attack from ozone:<ref>{{cite book |editor-last1=Craig |editor-first1=B. D.|editor-last2= Anderson|editor-first2=D. B. |title=Handbook of Corrosion Data |date=1995 |publisher=ASM International |location=Materials Park, Ohio |isbn=978-0-87170-518-1 |page=587}}</ref> <math chem display=block>\ce{Au + O2 -> }(\text{no reaction})</math> <math chem display=block>\ce{Au{} + O3 ->[{}\atop{t<100^\circ\text{C}}] }(\text{no reaction})</math> Some free [[halogen]]s react to form the corresponding gold halides.<ref>{{Cite book |last1=Wiberg |first1=Egon |last2=Wiberg |first2=Nils |last3=Holleman |first3=Arnold Frederick |name-list-style=amp |date=2001 |title=Inorganic Chemistry |edition=101st |publisher=Academic Press |isbn=978-0-12-352651-9 |page=1286 }}</ref> Gold is strongly attacked by fluorine at dull-red heat<ref>{{Cite book |url=https://books.google.com/books?id=Mtth5g59dEIC |title=Inorganic Chemistry |last1=Wiberg |first1=Egon |last2=Wiberg |first2=Nils |date=2001 |publisher=Academic Press |isbn=978-0-12-352651-9 |page=404}}</ref> to form [[gold(III) fluoride]] {{chem2|AuF3}}. Powdered gold reacts with chlorine at 180 °C to form [[gold(III) chloride]] {{chem2|AuCl3}}.<ref>{{harvnb|Wiberg|Wiberg|Holleman|2001|pp=1286–1287}}</ref> Gold reacts with bromine at 140 °C to form a combination of [[gold(III) bromide]] {{chem2|AuBr3}} and [[gold(I) bromide]] AuBr, but reacts very slowly with iodine to form [[gold(I) iodide]] AuI: <chem display=block>2 Au{} + 3 F2 ->[{}\atop\Delta] 2 AuF3</chem> <chem display=block>2 Au{} + 3 Cl2 ->[{}\atop\Delta] 2 AuCl3</chem> <chem display=block>2 Au{} + 2 Br2 ->[{}\atop\Delta] AuBr3{} + AuBr</chem> <chem display=block>2 Au{} + I2 ->[{}\atop\Delta] 2 AuI</chem> Gold does not react with sulfur directly,<ref name="library.lanl.gov">{{cite web |url=http://library.lanl.gov/cgi-bin/getfile?rc000062.pdf |last1=Emery |first1=J. F. |last2=Ledditcotte |first2=G. W. |title=Nuclear Science Series (NAS-NS 3036) The Radio Chemistry of Gold |date=May 1961 |agency=US Atomic Energy Commission |publisher=National Academy of Sciences — National Research Council — Subcommittee on Radio Chemistry |location=Oak Ridge, TN |url-status=live |access-date=24 February 2021 |archive-url=https://web.archive.org/web/20041110193206/http://library.lanl.gov/cgi-bin/getfile?rc000062.pdf |archive-date=10 November 2004}}</ref> but [[gold(III) sulfide]] can be made by passing [[hydrogen sulfide]] through a dilute solution of gold(III) chloride or [[chlorauric acid]]. Unlike sulfur, phosphorus reacts directly with gold at elevated temperatures to produce gold phosphide (Au<sub>2</sub>P<sub>3</sub>).<ref>{{cite journal |author1=Wolfgang Jeitschko |author2=Manfred H. Moller |title=The crystal structures of Au2P3 and Au7P10I, polyphosphides with weak Au–Au interactions |journal=Acta Crystallographica B |date=1979 |volume=35 |issue=3 |pages=573–579 |doi=10.1107/S0567740879004180 |bibcode=1979AcCrB..35..573J |language=en}}</ref> Gold readily dissolves in [[mercury (element)|mercury]] at room temperature to form an [[amalgam (chemistry)|amalgam]], and forms [[alloy]]s with many other metals at higher temperatures. These alloys can be produced to modify the hardness and other metallurgical properties, to control [[melting point]] or to create exotic colors.<ref name="utilisegold" /> Gold is unaffected by most acids. It does not react with [[hydrofluoric acid|hydrofluoric]], [[hydrochloric acid|hydrochloric]], [[hydrobromic acid|hydrobromic]], [[hydriodic acid|hydriodic]], [[sulfuric acid|sulfuric]], or [[nitric acid]]. It does react with [[selenic acid]], and is dissolved by [[aqua regia]], a 1:3 mixture of [[nitric acid]] and [[hydrochloric acid]]. Nitric acid oxidizes the metal to +3 ions, but only in minute amounts, typically undetectable in the pure acid because of the chemical equilibrium of the reaction. However, the ions are removed from the equilibrium by hydrochloric acid, forming {{chem2|AuCl4(−)}} ions, or [[chloroauric acid]], thereby enabling further oxidation: <chem display=block>2 Au{} + 6 H2SeO4 ->[{}\atop{200^\circ\text{C}}] Au2(SeO4)3{} + 3 H2SeO3{} + 3 H2O</chem> <chem display=block>Au{} + 4HCl{} + HNO3 -> HAuCl4{} + NO\uparrow + 2H2O </chem> Gold is similarly unaffected by most bases. It does not react with [[aqueous solution|aqueous]], [[solid]], or [[molten]] [[sodium hydroxide|sodium]] or [[potassium hydroxide]]. It does however, react with [[sodium cyanide|sodium]] or [[potassium cyanide]] under alkaline conditions when [[oxygen]] is present to form soluble complexes.<ref name="library.lanl.gov" /> Common [[oxidation state]]s of gold include +1 (gold(I) or aurous compounds) and +3 (gold(III) or auric compounds). Gold ions in solution are readily [[reduction (chemistry)|reduced]] and [[precipitation (chemistry)|precipitated]] as metal by adding any other metal as the [[reducing agent]]. The added metal is [[oxidation|oxidized]] and dissolves, allowing the gold to be displaced from solution and be recovered as a solid precipitate. === Rare oxidation states === Less common oxidation states of gold include −1, +2, and +5. The −1 oxidation state occurs in aurides, compounds containing the {{chem2|Au−}} [[anion]]. [[Caesium auride]] (CsAu), for example, crystallizes in the [[caesium chloride]] motif;<ref name="relativist_Au_Pt">{{Cite journal |title=Effects of relativistic motion of electrons on the chemistry of gold and platinum |first=Martin |last=Jansen |journal=Solid State Sciences |volume=7 |issue=12 |date=2005 |doi=10.1016/j.solidstatesciences.2005.06.015 |pages=1464–1474 |bibcode=2005SSSci...7.1464J|doi-access=free}}</ref> rubidium, potassium, and [[tetramethylammonium]] aurides are also known.<ref name="Holleman">{{cite book |last1=Holleman |first1=A. F. |last2=Wiberg |first2=E. |title=Inorganic Chemistry |publisher=Academic Press |location=San Diego |year=2001 |isbn=978-0-12-352651-9}}</ref> Gold has the highest [[electron affinity]] of any metal, at 222.8 kJ/mol, making {{chem2|Au−}} a stable species,<ref name="martin08">{{cite journal |last=Jansen |first=Martin |title=The chemistry of gold as an anion |journal=Chemical Society Reviews |date=2008 |volume=37 |issue=9 |pages=1826–1835 |doi=10.1039/b708844m |pmid=18762832}}</ref> analogous to the [[halide]]s. Gold also has a –1 oxidation state in covalent complexes with the [[Group 4 element|group 4]] transition metals, such as in titanium tetraauride and the analogous zirconium and hafnium compounds. These chemicals are expected to form gold-bridged [[dimer (chemistry)|dimer]]s in a manner similar to [[titanium(IV) hydride]].<ref>{{cite journal |title= Gold Behaves as Hydrogen in the Intermolecular Self-Interaction of Metal Aurides MAu<sub>4</sub> (M=Ti, Zr, and Hf) |first1= Jaehoon |last1= Jung |first2= Hyemi |last2= Kim |first3= Jong Chan |last3= Kim |first4= Min Hee |last4= Park |first5= Young-Kyu |last5= Han |journal= Chemistry: An Asian Journal |volume= 6 |issue= 3 |year= 2011 |pages= 868–872 |doi= 10.1002/asia.201000742 |pmid= 21225974 }}</ref> Gold(II) compounds are usually [[diamagnetic]] with Au–Au bonds such as [{{chem2|Au(CH2)2P(C6H5)2]2Cl2}}. The evaporation of a solution of {{chem2|Au(OH)3}} in concentrated {{chem2|H2SO4}} produces red crystals of [[gold(II) sulfate]], {{chem2|Au2(SO4)2}}. Originally thought to be a mixed-valence compound, it has been shown to contain {{chem2|Au2(4+)}} cations, analogous to the better-known [[mercury(I)]] ion, {{chem2|Hg2(2+)}}.<ref>{{Cite journal |last=Wickleder |first=Mathias S. |doi=10.1002/1521-3749(200109)627:9<2112::AID-ZAAC2112>3.0.CO;2-2 |date=2001 |title=AuSO<sub>4</sub>: A True Gold(II) Sulfate with an Au<sub>2</sub><sup>4+</sup> Ion |journal=Journal of Inorganic and General Chemistry |volume=627 |pages=2112–2114 |issue=9}}</ref><ref>{{Cite book |last=Wickleder |first=Mathias S. |title=Handbook of chalcogen chemistry: new perspectives in sulfur, selenium and tellurium |editor-first=Francesco A. |editor-last=Devillanova |publisher=Royal Society of Chemistry |date=2007 |isbn=978-0-85404-366-8 |pages=359–361 |url=https://books.google.com/books?id=IvGnUAaSqOsC&pg=PA359}}</ref> A gold(II) complex, the [[tetraxenonogold(II)]] cation, which contains [[xenon]] as a ligand, occurs in {{chem2|[AuXe4](Sb2F11)2}}.<ref>{{Cite journal |last1=Seidel |first1=S. |last2=Seppelt |first2=K. |title=Xenon as a Complex Ligand: The Tetra Xenono Gold(II) Cation in AuXe<sub>4</sub><sup>2+</sup>(Sb<sub>2</sub>F<sub>11</sub><sup>−</sup>)<sub>2</sub> |journal=Science |date=2000 |volume=290 |issue=5489 |pages=117–118 |doi=10.1126/science.290.5489.117 |pmid=11021792 |bibcode=2000Sci...290..117S}}</ref> In September 2023, a novel type of [[Perovskite (structure)|metal-halide perovskite material]] consisting of Au<sup>3+</sup> and Au<sup>2+</sup> cations in its crystal structure has been found.<ref>{{Cite web |last=University |first=Stanford |title=Striking rare gold: Researchers unveil new material infused with gold in an exotic chemical state |url=https://phys.org/news/2023-09-rare-gold-unveil-material-infused.html |access-date=2 October 2023 |website=phys.org |language=en}}</ref> It has been shown to be unexpectedly stable at normal conditions. [[Gold pentafluoride]], along with its derivative anion, {{chem2|AuF6-}}, and its [[difluorine complex]], [[gold heptafluoride]], is the sole example of gold(V), the highest verified oxidation state.<ref>{{Cite journal |last1=Riedel |first1=S. |last2=Kaupp |first2=M. |title=Revising the Highest Oxidation States of the 5d Elements: The Case of Iridium(+VII) |journal=Angewandte Chemie International Edition |date=2006 |volume=45 |issue=22 |pmid=16639770 |pages=3708–3711 |doi=10.1002/anie.200600274}}</ref> Some gold compounds exhibit ''[[aurophilicity|aurophilic bonding]]'', which describes the tendency of gold ions to interact at distances that are too long to be a conventional Au–Au bond but shorter than [[Van der Waals force|van der Waals bonding]]. The interaction is estimated to be comparable in strength to that of a [[hydrogen bond]]. Well-defined cluster compounds are numerous.<ref name="Holleman" /> In some cases, gold has a fractional oxidation state. A representative example is the octahedral species {{chem2|{Au([[triphenylphosphine|P(C6H5)3]])}6(2+)}}. ==Origin== ===Gold production in the universe=== [[File:Vredefort crater cross section 2.png|thumb|upright=1.8|Schematic of a NE (left) to SW (right) cross-section through the 2.020-billion-year-old [[Vredefort impact structure]] in [[South Africa]] and how it distorted the contemporary geological structures. The present erosion level is shown. [[Johannesburg]] is located where the [[Witwatersrand Basin]] (the yellow layer) is exposed at the "present surface" line, just inside the crater rim, on the left. Not to scale.]] Gold is thought to have been produced in [[supernova nucleosynthesis]], and from the [[Neutron star merger|collision of neutron stars]],<ref>{{cite news |url=https://www.cfa.harvard.edu/news/2013-19 |title=Earth's Gold Came from Colliding Dead Stars |work=David A. Aguilar & Christine Pulliam |publisher=cfa.harvard.edu |date=17 July 2013 |access-date=18 February 2018}}</ref> and to have been present in the [[solar nebula|dust]] from which the [[Solar System]] formed.<ref>{{Cite journal |doi=10.1086/190111 |title=Nucleosynthesis of Heavy Elements by Neutron Capture |date=1965 |last1=Seeger |first1=Philip A. |last2=Fowler |first2=William A. |last3=Clayton |first3=Donald D. |journal=The Astrophysical Journal Supplement Series |volume=11 |page=121 |bibcode=1965ApJS...11..121S |url=http://tigerprints.clemson.edu/cgi/viewcontent.cgi?article=1307&context=physastro_pubs}}</ref> Traditionally, gold in the universe is thought to have formed by the [[r-process]] (rapid neutron capture) in [[supernova nucleosynthesis]],<ref>{{cite web |url=http://chandra.harvard.edu/xray_sources/supernovas.html |title=Supernovas & Supernova Remnants |publisher=[[Chandra X-ray Observatory]] |access-date=28 February 2014}}</ref> but more recently it has been suggested that gold and other elements heavier than [[iron]] may also be produced in quantity by the r-process in the [[neutron star merger|collision]] of [[neutron star]]s.<ref>{{cite journal |last1=Berger |first1=E. |first2=W. |last2=Fong |first3=R. |last3=Chornock |date=2013 |title=An r-process Kilonova Associated with the Short-hard GRB 130603B |journal=The Astrophysical Journal Letters |volume=774 |issue=2 |page=4 |doi=10.1088/2041-8205/774/2/L23 |arxiv=1306.3960 |bibcode=2013ApJ...774L..23B|s2cid=669927 }}</ref> In both cases, satellite spectrometers at first only indirectly detected the resulting gold.<ref>"we have no spectroscopic evidence that [such] elements have truly been produced," wrote author Stephan Rosswog.{{cite journal |last=Rosswog |first=Stephan |date=29 August 2013 |title=Astrophysics: Radioactive glow as a smoking gun |journal=[[Nature (journal)|Nature]] |volume=500 |issue=7464 |pages=535–536 |doi=10.1038/500535a |bibcode=2013Natur.500..535R |pmid=23985867|s2cid=4401544 }}</ref> However, in August 2017, the spectroscopic signatures of heavy elements, including gold, were observed by electromagnetic observatories in the [[GW170817]] neutron star merger event, after [[gravitational wave]] detectors confirmed the event as a neutron star merger.<ref>{{cite news |title=LIGO and Virgo make first detection of gravitational waves produced by colliding neutron stars |url=https://www.ligo.org/detections/GW170817/press-release/pr-english.pdf |archive-url=https://web.archive.org/web/20171031030151/http://www.ligo.org/detections/GW170817/press-release/pr-english.pdf |archive-date=31 October 2017 |url-status=live |publisher=[[LIGO]] & [[Virgo interferometer|Virgo]] collaborations |date=16 October 2017 |access-date=15 February 2018}}</ref> Current astrophysical models suggest that this single neutron star merger event generated between 3 and 13 [[Earth mass]]es of gold. This amount, along with estimations of the rate of occurrence of these neutron star merger events, suggests that such mergers may produce enough gold to account for most of the abundance of this element in the universe.<ref>{{cite news |title=Neutron star mergers may create much of the universe's gold |work=Sid Perkins |publisher=Science AAAS |url=https://www.science.org/content/article/neutron-star-mergers-may-create-much-universe-s-gold |date=20 March 2018 |access-date=24 March 2018}}</ref> ===Asteroid origin theories=== Because the Earth was molten [[History of Earth|when it was formed]], almost all of the gold present in the [[early Earth]] probably sank into the [[core (geology)|planetary core]]. Therefore, as hypothesized in one model, most of the gold in the Earth's [[crust (geology)|crust]] and [[mantle (geology)|mantle]] is thought to have been delivered to Earth by [[asteroid impact]]s during the [[Late Heavy Bombardment]], about 4 billion years ago.<ref name="Willbold 2011">{{cite journal |last2=Elliott |first2=Tim |last3=Moorbath |first3=Stephen |date=2011 |title=The tungsten isotopic composition of the Earth's mantle before the terminal bombardment |journal=Nature |volume=477 |issue=7363 |pages=195–8 |bibcode=2011Natur.477..195W |doi=10.1038/nature10399 |pmid=21901010 |last1=Willbold |first1=Matthias|s2cid=4419046 }}</ref><ref name="Battison-2011">{{cite news |url=https://www.bbc.co.uk/news/science-environment-14827624 |title=Meteorites delivered gold to Earth |last=Battison |first=Leila |date=8 September 2011 |work=[[BBC]] }}</ref> Gold which is reachable by humans has, in one case, been associated with a particular asteroid impact. The asteroid that formed [[Vredefort impact structure]] 2.020 billion years ago is often credited with seeding the [[Witwatersrand basin]] in [[South Africa]] with the richest gold deposits on earth.<ref>{{cite web |url=http://superiormining.com/properties/south_africa/mangalisa/geology/ |title=Mangalisa Project |publisher=Superior Mining International Corporation |access-date=29 December 2014}}</ref><ref>{{cite journal |last1=Therriault |first1=A. M. |first2=R. A. F. |last2=Grieve |first3=W. U. |last3=Reimold |title=Original size of the Vredefort Structure: Implications for the geological evolution of the Witwatersrand Basin |journal=Meteoritics |volume=32 |pages=71–77 |date=1997 |bibcode=1997M&PS...32...71T |name-list-style=amp |doi=10.1111/j.1945-5100.1997.tb01242.x|doi-access=free }}</ref><ref>[https://web.archive.org/web/20120327184158/http://www.cosmosmagazine.com/news/2101/meteor-craters-may-hold-untapped-wealth Meteor craters may hold untapped wealth]. Cosmos Magazine (28 July 2008). Retrieved on 12 September 2013.</ref><ref>{{Cite journal |last1=Corner |first1=B. |last2=Durrheim |first2=R. J. |last3=Nicolaysen |first3=L. O. |title=Relationships between the Vredefort structure and the Witwatersrand basin within the tectonic framework of the Kaapvaal craton as interpreted from regional gravity and aeromagnetic data |doi=10.1016/0040-1951(90)90089-Q |journal=Tectonophysics |volume=171 |issue=1 |pages=49–61 |year=1990 |bibcode=1990Tectp.171...49C}}</ref> However, this scenario is now questioned. The gold-bearing [[Witwatersrand]] rocks were laid down between 700 and 950 million years before the Vredefort impact.<ref name="McCarthy">McCarthy, T., Rubridge, B. (2005). ''The Story of Earth and Life''. Struik Publishers, Cape Town. pp. 89–90, 102–107, 134–136. {{ISBN|1 77007 148 2}}</ref><ref name="Norman">Norman, N., Whitfield, G. (2006) ''Geological Journeys''. Struik Publishers, Cape Town. pp. 38–49, 60–61. {{ISBN|9781770070622}}</ref> These gold-bearing rocks had furthermore been covered by a thick layer of Ventersdorp lavas and the [[Transvaal Basin|Transvaal Supergroup]] of rocks before the meteor struck, and thus the gold did not actually arrive in the asteroid/meteorite. What the Vredefort impact achieved, however, was to distort the [[Witwatersrand basin]] in such a way that the gold-bearing rocks were brought to the present [[erosion surface]] in [[Johannesburg]], on the [[Witwatersrand]], just inside the rim of the original {{cvt|300|km|adj=on}} diameter crater caused by the meteor strike. The discovery of the deposit in 1886 launched the [[Witwatersrand Gold Rush]]. Some 22% of all the gold that is ascertained to exist today on Earth has been extracted from these Witwatersrand rocks.<ref name="Norman" /> ===Mantle return theories=== Much of the rest of the gold on Earth is thought to have been incorporated into the planet since its very beginning, as [[planetesimals]] formed the [[Mantle (geology)|mantle]]. In 2017, an international group of scientists established that gold "came to the Earth's surface from the deepest regions of our planet",<ref>{{cite web |author=University of Granada |title=Scientists reveal the mystery about the origin of gold |website=ScienceDaily |date=21 November 2017 |access-date=27 March 2018 |url=https://www.sciencedaily.com/releases/2017/11/171121095128.htm}}</ref> the mantle, as evidenced by their findings at [[Deseado Massif]] in the [[Argentinian Patagonia]].<ref>{{cite journal |last1=Tassara |first1=Santiago |last2=González-Jiménez |first2=José M. |last3=Reich |first3=Martin |last4=Schilling |first4=Manuel E. |last5=Morata |first5=Diego |last6=Begg |first6=Graham |last7=Saunders |first7=Edward |last8=Griffin |first8=William L. |last9=O’Reilly |first9=Suzanne Y.|last10=Grégoire|first10=Michel |last11=Barra |first11=Fernando |last12=Corgne |first12=Alexandre |title=Plume-subduction interaction forms large auriferous provinces |journal=Nature Communications |volume=8 |issue=1 |pages=843 |year=2017 |issn=2041-1723 |doi=10.1038/s41467-017-00821-z |pmid=29018198 |pmc=5634996 |bibcode=2017NatCo...8..843T}}</ref>{{clarify|reason=this directly contradicts the first paragraph of the next section|date=April 2019}} == Occurrence == [[File:Gold nugget (Australia) 4 (16848647509).jpg|thumb|left|upright=0.7|[[Native metal|Native gold]].]] On Earth, gold is found in [[ore]]s in rock formed from the [[Precambrian]] time onward.<ref name="La Niece" /> It most often occurs as a [[native metal]], typically in a metal [[solid solution]] with silver (i.e. as a gold/silver [[alloy]]). Such alloys usually have a silver content of 8–10%. [[Electrum]] is elemental gold with more than 20% silver, and is commonly known as [[white gold]]. Electrum's color runs from golden-silvery to silvery, dependent upon the silver content. The more silver, the lower the [[specific gravity]]. Native gold occurs as very small to microscopic particles embedded in rock, often together with [[quartz]] or [[sulfide mineral]]s such as "[[fool's gold]]", which is a [[pyrite]].<ref>{{cite web |url=http://arizonagoldprospectors.com/formation.htm |title=Formation of Lode Gold Deposits |author=Heike, Brian |url-status=dead |archive-url=https://web.archive.org/web/20130122100747/http://arizonagoldprospectors.com/formation.htm |archive-date=22 January 2013 |publisher=Arizona Gold Prospectors|access-date=24 February 2021}}</ref> These are called [[lode]] deposits. The metal in a native state is also found in the form of free flakes, grains or larger [[Gold nugget|nuggets]]<ref name="La Niece" /> that have been eroded from rocks and end up in [[alluvial]] deposits called [[placer deposit]]s. Such free gold is always richer at the exposed surface of gold-bearing veins, owing to the [[oxidation]] of accompanying minerals followed by weathering; and by washing of the dust into streams and rivers, where it collects and can be welded by water action to form nuggets. Gold sometimes occurs combined with [[tellurium]] as the [[mineral]]s [[calaverite]], [[krennerite]], [[nagyagite]], [[petzite]] and [[sylvanite]] (see [[telluride mineral]]s), and as the rare bismuthide maldonite ({{chem2|Au2Bi}}) and antimonide [[aurostibite]] ({{chem2|AuSb2}}). Gold also occurs in rare alloys with [[copper]], [[lead]], and [[mercury (element)|mercury]]: the minerals [[auricupride]] ({{chem2|Cu3Au}}), novodneprite ({{chem2|AuPb3}}) and weishanite ({{chem2|(Au,Ag)3Hg2}}). A 2004 research paper suggests that microbes can sometimes play an important role in forming gold deposits, transporting and precipitating gold to form grains and nuggets that collect in alluvial deposits.<ref>{{cite web |url=http://www.abc.net.au/science/news/enviro/EnviroRepublish_1032376.htm |title=Environment & Nature News – Bugs grow gold that looks like coral |date=28 January 2004 |access-date=22 July 2006 |publisher=abc.net.au}} This is doctoral research undertaken by Frank Reith at the Australian National University, published 2004.</ref> A 2013 study has claimed water in faults vaporizes during an earthquake, depositing gold. When an earthquake strikes, it moves along a [[fault (geology)|fault]]. Water often lubricates faults, filling in fractures and jogs. About {{convert|10|km}} below the surface, under very high temperatures and pressures, the water carries high concentrations of carbon dioxide, silica, and gold. During an earthquake, the fault jog suddenly opens wider. The water inside the void instantly vaporizes, flashing to steam and forcing silica, which forms the mineral quartz, and gold out of the fluids and onto nearby surfaces.<ref>{{cite web |url=https://news.yahoo.com/earthquakes-turn-water-gold-180356174.html |title=Earthquakes Turn Water into Gold |date=17 March 2013 |access-date=18 March 2013}}</ref> === Seawater === The world's [[ocean]]s contain gold. Measured concentrations of gold in the Atlantic and Northeast Pacific are 50–150 [[femtomolar|femtomol]]/L or 10–30 parts per [[quadrillion]] (about 10–30 g/km<sup>3</sup>). In general, gold concentrations for south Atlantic and central Pacific samples are the same (~50 femtomol/L) but less certain. Mediterranean deep waters contain slightly higher concentrations of gold (100–150 femtomol/L) attributed to wind-blown dust or rivers. At 10 parts per quadrillion the Earth's [[oceans]] would hold 15,000 tonnes of gold.<ref>{{Cite journal |doi=10.1016/0012-821X(90)90060-B |title=Gold in seawater |first1=K. |last1=Kenison Falkner |author-link1=Kelly Falkner|journal=Earth and Planetary Science Letters |volume=98 |date=1990 |pages=208–221 |last2=Edmond |first2=J. |issue=2 |bibcode=1990E&PSL..98..208K}}</ref> These figures are three orders of magnitude less than reported in the literature prior to 1988, indicating contamination problems with the earlier data. A number of people have claimed to be able to economically recover gold from [[sea water]], but they were either mistaken or acted in an intentional deception. [[Prescott Jernegan]] ran a gold-from-seawater swindle in the [[United States]] in the 1890s, as did an English fraudster in the early 1900s.<ref>Plazak, Dan ''A Hole in the Ground with a Liar at the Top'' (Salt Lake: Univ. of Utah Press, 2006) {{ISBN|0-87480-840-5}} (contains a chapter on gold-from seawater swindles)</ref> [[Fritz Haber]] did research on the extraction of gold from sea water in an effort to help pay [[Germany]]'s reparations following [[World War I]].<ref>{{Cite journal |title=Das Gold im Meerwasser |first=F. |last=Haber |volume=40 |issue=11 |date=1927 |doi=10.1002/ange.19270401103 |pages=303–314 |journal=Zeitschrift für Angewandte Chemie|bibcode=1927AngCh..40..303H }}</ref> Based on the published values of 2 to 64 ppb of gold in seawater, a commercially successful extraction seemed possible. After analysis of 4,000 water samples yielding an average of 0.004 ppb, it became clear that extraction would not be possible and he ended the project.<ref>{{Cite journal |doi=10.1016/0375-6742(88)90051-9 |title=Concentration of gold in natural waters |first=J. B. |last=McHugh |journal=Journal of Geochemical Exploration |volume=30 |date=1988 |pages=85–94 |issue=1–3 |bibcode=1988JCExp..30...85M |url=https://zenodo.org/record/1258491 |archive-url=https://web.archive.org/web/20200307233511/https://zenodo.org/record/1258491 |url-status=dead |archive-date=7 March 2020}}</ref><!--10.1007/BF01497020--> == History == [[File:Grave offerings.jpg|thumb|Oldest golden artifacts in the world (4600–4200 BC) from Varna necropolis, Bulgaria — grave offerings on exposition in [[Varna Archaeological Museum|Varna Museum]].]] [[File:Indian gold tribute donor Apadana.jpg|thumb|upright|An Indian tribute-bearer at [[Apadana]], from the [[Achaemenid Empire|Achaemenid]] [[satrapy]] of ''[[Hindush]]'', carrying gold on a yoke, circa 500 BC.<ref name="CDA">"Furthermore the second member of Delegation XVIII is carrying four small but evidently heavy jars on a yoke, probably containing the gold dust which was the tribute paid by the Indians." in {{cite book |last1=Iran |first1=Délégation archéologique française en |title=Cahiers de la Délégation archéologique française en Iran |date=1972 |publisher=Institut français de recherches en Iran (section archéologique) |pages=146 |url=https://books.google.com/books?id=itIRAQAAMAAJ}}</ref>]] [[File:Gold Museum, Bogota (36145671394).jpg|thumb|right|The [[Muisca raft]], between circa 600–1600 AD. The figure refers to the ceremony of the legend of [[El Dorado]]. The ''[[zipa]]'' used to cover his body in gold dust, and from his [[Muisca raft|raft]], he offered treasures to the ''[[Guatavita]]'' goddess in the middle of the [[sacred lake]]. This old Muisca tradition became the origin of the legend of El Dorado.<br /><small>This Muisca raft figure is on display in the [[Gold Museum, Bogotá]], Colombia.</small>]] The earliest recorded metal employed by humans appears to be gold, which can be found [[native metal|free]] or "[[native metal|native]]". Small amounts of natural gold have been found in Spanish caves used during the late [[Paleolithic]] period, {{Circa|40,000 BC}}.<ref>{{cite web |url=http://www.gold-eagle.com/gold_digest/history_gold.html |title=History of Gold |publisher=Gold Digest |access-date=4 February 2007}}</ref> The oldest gold artifacts in the world are from [[Bulgaria]] and are dating back to the 5th millennium BC (4,600 BC to 4,200 BC), such as those found in the [[Varna Necropolis]] near Lake Varna and the [[Black Sea]] coast, thought to be the earliest "well-dated" finding of gold artifacts in history.<ref>{{cite web | url=https://www.smithsonianmag.com/travel/varna-bulgaria-gold-graves-social-hierarchy-prehistoric-archaelogy-smithsonian-journeys-travel-quarterly-180958733/ | title=Mystery of the Varna Gold: What Caused These Ancient Societies to Disappear? }}</ref><ref name="La Niece">{{cite book |last=La Niece |first=Susan (senior metallurgist in the British Museum Department of Conservation and Scientific Research) |url=https://books.google.com/books?id=oAfITjcHiZ0C |title=Gold |page=10 |publisher=Harvard University Press |access-date=10 April 2012 |isbn=978-0-674-03590-4 |date=15 December 2009}}</ref><ref>{{cite web | url=https://www.smithsonianmag.com/smart-news/oldest-gold-object-unearthed-bulgaria-180960093/ | title=World's Oldest Gold Object May Have Just Been Unearthed in Bulgaria }}</ref> Several prehistoric Bulgarian finds are considered no less old – the golden treasures of Hotnitsa, [[Durankulak]], artifacts from the Kurgan settlement of Yunatsite near [[Pazardzhik]], the golden treasure Sakar, as well as beads and gold jewelry found in the Kurgan settlement of [[Provadia]] – [[Solnitsata]] ("salt pit"). However, Varna gold is most often called the oldest since this treasure is the largest and most diverse.<ref>{{cite web | url=https://afrinik.com/archaeologists-have-discovered-the-oldest-treasure-in-the-world/ | title=Archaeologists have discovered the oldest treasure in the world – Afrinik | date=15 May 2021 }}</ref> Gold artifacts probably made their first appearance in Ancient Egypt at the very beginning of the pre-dynastic period, at the end of the fifth millennium BC and the start of the fourth, and smelting was developed during the course of the 4th millennium; gold artifacts appear in the archeology of Lower Mesopotamia during the early 4th millennium.<ref>Sutherland, C.H.V, Gold (London, Thames & Hudson, 1959) p 27 ff.</ref> As of 1990, gold artifacts found at the [[Wadi Qana]] cave cemetery of the [[4th millennium BC]] in [[West Bank]] were the earliest from the Levant.<ref name="Gopher, Tsuk, Shalev and Gophna">{{cite journal |last1=Gopher |first1=A. |first2=T. |last2=Tsuk |first3=S. |last3=Shalev |first4=R. |last4=Gophna |name-list-style=amp |title=Earliest Gold Artifacts in the Levant |date=August–October 1990 |journal=Current Anthropology |volume=31 |issue=4 |pages=436–443 |jstor=2743275 |doi=10.1086/203868|s2cid=143173212 }}</ref> Gold artifacts such as the [[golden hats]] and the [[Nebra disk]] appeared in Central Europe from the 2nd millennium BC [[European Bronze Age|Bronze Age]]. The oldest known map of a gold mine was drawn in the 19th Dynasty of Ancient Egypt (1320–1200 BC), whereas the first written reference to gold was recorded in the 12th Dynasty around 1900 BC.<ref>Pohl, Walter L. (2011) ''Economic Geology Principles and Practice''. Wiley. p. 208. {{doi|10.1002/9781444394870.ch2}}. {{ISBN|9781444394870 }}</ref> [[Egyptian hieroglyph]]s from as early as 2600 BC describe gold, which King [[Tushratta]] of the [[Mitanni]] claimed was "more plentiful than dirt" in Egypt.<ref>{{cite book |last1=Montserrat |first1=Dominic |url=https://books.google.com/books?id=bfRbY4gInsQC |title=Akhenaten: History, Fantasy and Ancient Egypt |isbn=978-0-415-30186-2 |date=21 February 2003|publisher=Psychology Press }}</ref> Egypt and especially [[Nubia]] had the resources to make them major gold-producing areas for much of history. One of the earliest known maps, known as the [[Turin Papyrus Map]], shows the plan of a [[gold mine]] in Nubia together with indications of the local [[geology]]. The primitive working methods are described by both [[Strabo]] and [[Diodorus Siculus]], and included [[fire-setting]]. Large mines were also present across the [[Red Sea]] in what is now [[Saudi Arabia]]. [[File:Golden crown Armento Staatliche Antikensammlungen 01.jpg|thumb|left|Ancient golden [[Kritonios Crown]], funerary or marriage material, 370–360 BC; from a grave in [[Armento]], [[Basilicata]]]] Gold is mentioned in the [[Amarna letters]] numbered [[Amarna letter EA 19|19]]<ref>[[William L. Moran|Moran, William L.]], 1987, 1992. The Amarna Letters, pp. 43–46.</ref> and [[Amarna letter EA 26|26]]<ref>[[William L. Moran|Moran, William L.]] 1987, 1992. The Amarna Letters. EA 245, "To the Queen Mother: Some Missing Gold Statues", pp. 84–86.</ref> from around the 14th century BC.<ref>[https://www.britannica.com/biography/Akhenaten "Akhenaten"] {{Webarchive|url=https://web.archive.org/web/20080611092705/http://www.britannica.com/eb/article-9005276/Akhenaton |date=11 June 2008 }}. ''[[Encyclopaedia Britannica]]''</ref><ref>Dodson, Aidan and Hilton, Dyan (2004). ''The Complete Royal Families of Ancient Egypt''. Thames & Hudson. {{ISBN|0-500-05128-3}}</ref> Gold is mentioned frequently in the [[Old Testament]], starting with [[Book of Genesis|Genesis]] 2:11 (at [[Havilah]]), the story of the [[golden calf]], and many parts of the temple including the [[Menorah (Temple)|Menorah]] and the golden altar. In the [[New Testament]], it is included with the gifts of the [[magi]] in the first chapters of Matthew. The [[Book of Revelation]] 21:21 describes the city of [[New Jerusalem]] as having streets "made of pure gold, clear as crystal". Exploitation of gold in the south-east corner of the [[Black Sea]] is said to date from the time of [[Midas]], and this gold was important in the establishment of what is probably the world's earliest coinage in [[Lydia]] around 610 BC.<ref name="lion" /> The legend of the [[golden fleece]] dating from eighth century BCE may refer to the use of fleeces to trap gold dust from [[placer deposit]]s in the ancient world. From the 6th or 5th century BC, the [[Chu (state)]] circulated the [[Ying Yuan]], one kind of square gold coin. In [[Roman metallurgy]], new methods for extracting gold on a large scale were developed by introducing [[hydraulic mining]] methods, especially in [[Hispania]] from 25 BC onwards and in [[Dacia]] from 106 AD onwards. One of their largest mines was at [[Las Medulas]] in [[León (province)|León]], where seven long [[aqueduct (watercourse)|aqueducts]] enabled them to sluice most of a large alluvial deposit. The mines at [[Roşia Montană]] in [[Transylvania]] were also very large, and until very recently,{{when|date=January 2024}} still mined by opencast methods. They also exploited smaller deposits in [[Roman Britain|Britain]], such as placer and hard-rock deposits at [[Dolaucothi]]. The various methods they used are well described by [[Pliny the Elder]] in his [[encyclopedia]] ''[[Naturalis Historia]]'' written towards the end of the first century AD. During [[Mansa Musa]]'s (ruler of the [[Mali Empire]] from 1312 to 1337) [[hajj]] to [[Mecca]] in 1324, he passed through [[Cairo]] in July 1324, and was reportedly accompanied by a [[camel train]] that included thousands of people and nearly a hundred camels where he gave away so much gold that it depressed the price in Egypt for over a decade, causing high [[inflation]].<ref>[https://web.archive.org/web/20060524015912/http://www.blackhistorypages.net/pages/mansamusa.php Mansa Musa]. Black History Pages</ref> A contemporary Arab historian remarked: {{blockquote|Gold was at a high price in Egypt until they came in that year. The mithqal did not go below 25 dirhams and was generally above, but from that time its value fell and it cheapened in price and has remained cheap till now. The mithqal does not exceed 22 dirhams or less. This has been the state of affairs for about twelve years until this day by reason of the large amount of gold which they brought into Egypt and spent there [...].|sign=[[Chihab Al-Umari]]|source=Kingdom of Mali<ref>{{cite web |title=Kingdom of Mali – Primary Source Documents |url=http://www.bu.edu/africa/outreach/resources/k_o_mali/ |website=African studies Center |publisher=[[Boston University]] |access-date=30 January 2012}}</ref>}} [[File:Monnaie de Bactriane, Eucratide I, 2 faces.jpg|thumb|Gold coin of [[Eucratides I]] (171–145 BC), one of the Hellenistic rulers of ancient [[Ai-Khanoum]]. This is the largest known gold coin minted in antiquity ({{cvt|169.2|g}}; {{cvt|58|mm}}).<ref>{{cite book |last1=Monnaie |first1=Eucratide I. (roi de Bactriane) Autorité émettrice de |title=[Monnaie : 20 Statères, Or, Incertain, Bactriane, Eucratide I] |url=https://gallica.bnf.fr/ark:/12148/btv1b8510709q}}</ref>]] The European exploration of the Americas was fueled in no small part by reports of the gold ornaments displayed in great profusion by [[Indigenous peoples of the Americas|Native American]] peoples, especially in [[Mesoamerica]], [[Peru]], [[Ecuador]] and [[Colombia]]. The [[Aztec]]s regarded gold as the product of the gods, calling it literally "god excrement" (''teocuitlatl'' in [[Nahuatl]]), and after [[Moctezuma II]] was killed, most of this gold was shipped to Spain.<ref>{{Cite book |first1=Frances |last1=Berdan |first2=Patricia Rieff |last2=Anawalt |title=The Codex Mendoza |volume=2 |page=151 |publisher=[[University of California Press]] |date=1992 |isbn=978-0-520-06234-4}}</ref> However, for the [[indigenous peoples of North America]] gold was considered useless and they saw much greater value in other [[minerals]] which were directly related to their utility, such as [[obsidian]], [[flint]], and [[slate]].<ref>[https://web.archive.org/web/20120112010110/http://www.sierranevadavirtualmuseum.com/docs/galleries/history/culture/shadows.htm Sierra Nevada Virtual Museum]. Sierra Nevada Virtual Museum. Retrieved on 4 May 2012.</ref> [[El Dorado]] is applied to a legendary story in which precious stones were found in fabulous abundance along with gold coins. The concept of El Dorado underwent several transformations, and eventually accounts of the previous myth were also combined with those of a legendary lost city. El Dorado, was the term used by the Spanish Empire to describe a mythical tribal chief (zipa) of the Muisca native people in [[Colombia]], who, as an initiation rite, covered himself with gold dust and submerged in [[Lake Guatavita]]. The legends surrounding El Dorado changed over time, as it went from being a man, to a city, to a kingdom, and then finally to an empire.{{cn|date=January 2024}} Beginning in the [[early modern period]], European [[Age of Discovery|exploration]] and [[Colonisation of Africa|colonization]] of [[West Africa]] was driven in large part by reports of gold deposits in the region, which was eventually referred to by Europeans as the "[[Gold Coast (region)|Gold Coast]]".<ref>{{cite book | first=James Maxwell | last=Anderson|title=The History of Portugal | publisher=Greenwood Publishing Group | year=2000 | isbn=0-313-31106-4 | url=https://books.google.com/books?id=UoryGn9o4x0C | ref=refAnderson}}</ref> From the late 15th to early 19th centuries, European trade in the region was primarily focused in gold, along with [[ivory]] and [[Atlantic slave trade|slaves]].<ref>{{Cite book|last=Newitt|first=Malyn|url=https://books.google.com/books?id=fsoWg1yXKQUC&q=portuguese+in+ghana|title=The Portuguese in West Africa, 1415–1670: A Documentary History|date=28 June 2010|publisher=Cambridge University Press|isbn=978-1-139-49129-7|language=en}}</ref> The gold trade in West Africa was dominated by the [[Ashanti Empire]], who initially traded with the [[Portuguese Empire|Portuguese]] before branching out and trading with [[British Empire|British]], [[French colonial empire|French]], [[Spanish Empire|Spanish]] and [[Danish colonial empire|Danish]] merchants.<ref name="Green, Toby">{{cite book |last1=Green |first1=Toby |title=A fistful of shells : West Africa from the rise of the slave trade to the age of revolution |date=31 January 2019 |location=London |isbn=978-0-241-00328-2 |pages=108, 247 |edition=Penguin Books Ltd. Kindle-Version}}</ref> British desires to secure control of West African gold deposits played a role in the [[Anglo-Ashanti wars]] of the late 19th century, which saw the Ashanti Empire [[Gold Coast (British colony)|annexed by Britain]].<ref>{{cite book |last=Edgerton |first=Robert B. |year=2010 |title=The Fall of the Asante Empire: The Hundred-Year War For Africa's Gold Coast |publisher=Simon and Schuster |isbn=9781451603736 }}</ref> Gold played a role in western culture, as a cause for desire and of corruption, as told in children's [[fable]]s such as [[Rumpelstiltskin]]—where Rumpelstiltskin turns hay into gold for the peasant's daughter in return for her child when she becomes a princess—and the stealing of the hen that lays golden eggs in [[Jack and the Beanstalk]]. The top prize at the [[Olympic Games]] and many other sports competitions is the [[gold medal]]. 75% of the presently accounted for gold has been extracted since 1910, two-thirds since 1950. One main goal of the [[alchemy|alchemists]] was to produce gold from other substances, such as [[lead]] — presumably by the interaction with a mythical substance called the [[philosopher's stone]]. Trying to produce gold led the alchemists to systematically find out what can be done with substances, and this laid the foundation for today's [[chemistry]], which can produce gold (albeit uneconomically) by using [[nuclear transmutation]].<ref>{{cite web |url=https://www.scientificamerican.com/article/fact-or-fiction-lead-can-be-turned-into-gold/ |title=Fact or Fiction?: Lead Can Be Turned into Gold |author=Matson, John |date=31 January 2014 |website=scientificamerican.com |access-date=21 November 2021}}</ref> Their symbol for gold was the circle with a point at its center (☉), which was also the [[astrology|astrological]] symbol and the ancient [[Chinese character]] for the [[Sun]]. The [[Dome of the Rock]] is covered with an ultra-thin golden glassier. The [[Sikh]] Golden temple, the [[Harmandir Sahib]], is a building covered with gold. Similarly the [[Wat Phra Kaew]] emerald [[Buddhism|Buddhist]] [[temple]] ([[wat]]) in [[Thailand]] has ornamental gold-leafed statues and roofs. Some European king and queen's [[crown (headgear)|crowns]] were made of gold, and gold was used for the [[bridal crown]] since antiquity. An ancient Talmudic text circa 100 AD describes [[Rachel, wife of Rabbi Akiva]], receiving a "Jerusalem of Gold" (diadem). A Greek burial crown made of gold was found in a grave circa 370 BC. <gallery mode="packed" heights="170px"> Gold leaf MET DP260372.jpg|[[Minoan civilization|Minoan]] jewellery, 2300–2100 BC, gold, [[Metropolitan Museum of Art]], New York Earrings from Shulgi.JPG|[[Sumer]]ian earrings with [[cuneiform]] inscriptions, 2093–2046 BC, gold, [[Sulaymaniyah Museum]], [[Sulaymaniyah]], Iraq File:Aegina treasure 10.jpg|Minoan cup, part of the [[Aegina Treasure]], 1850–1550 BC, gold, [[British Museum]]<ref>{{cite book|last1=La Niece|first1=Susan|title=Gold|date=2009|publisher=The British Museum Press|isbn=978-0-7141-5076-5|page=8|url=|language=en}}</ref> Statuette of Amun MET DT553.jpg|[[Ancient Egypt]]ian statuette of [[Amun]], 945–715 BC, gold, Metropolitan Museum of Art Anillo de Sheshonq (46627183381).jpg|Ancient Egyptian signet ring, 664–525 BC, gold, British Museum File:Openwork dagger handle-IMG 4418-black.jpg|[[Ancient China|Ancient Chinese]] cast openwork dagger hilt, 6th–5th centuries BC, gold, British Museum<ref>{{cite book|last1=La Niece|first1=Susan|title=Gold|date=2009|publisher=The British Museum Press|isbn=978-0-7141-5076-5|page=25|url=|language=en}}</ref> Gold stater MET DP138743.jpg|[[Ancient Greece|Ancient Greek]] [[stater]], 323–315 BC, gold, Metropolitan Museum of Art Gold funerary wreath MET DP257471.jpg|[[Etruscans|Etruscan]] funerary wreath, 4th–3rd century BC, gold, Metropolitan Museum of Art Gold aureus of Hadrian MET DP104782b.jpg|[[Roman Empire|Roman]] [[aureus]] of [[Hadrian]], 134–138 AD, gold, Metropolitan Museum of Art Lime Container (Poporo) MET DT1262.jpg|[[Quimbaya civilization|Quimbaya]] lime container, 5th–9th century, gold, Metropolitan Museum of Art File:British Museum - Room 41 (20626313758).jpg|[[Anglo-Saxon art|Anglo-Saxon]] belt buckle from [[Sutton Hoo]] with a [[niello]] [[Interlace (art)|interlace]] pattern, 7th century, gold, British Museum<ref>{{cite book|last1=La Niece|first1=Susan|title=Gold|date=2009|publisher=The British Museum Press|isbn=978-0-7141-5076-5|page=76|url=|language=en}}</ref> Byzantium, 11th century - Scyphate - 2001.25 - Cleveland Museum of Art.tif|[[Byzantine empire|Byzantine]] [[scyphate]], 1059–1067, gold, [[Cleveland Museum of Art]], [[Cleveland]], [[Ohio]], USA Double Bat-Head Figure Pendant MET DT935.jpg|[[Pre-Columbian era|Pre-Columbian]] pendant with two bat-head warriors who carry spears, 11th–16th century, gold, Metropolitan Museum of Art File:AHOTWgold lama.JPG|[[Inca Empire|Inca]] hollow model of a llama, 14th-15th centuries, gold, British Museum<ref>{{cite book|last1=La Niece|first1=Susan|title=Gold|date=2009|publisher=The British Museum Press|isbn=978-0-7141-5076-5|page=66|url=|language=en}}</ref> File:The Judgement of Paris, Waddeson Bequest.jpg|[[Renaissance art|Renaissance]] hat badge that shows the [[Judgment of Paris]], 16th century, enamelled gold, British Museum<ref>{{cite book|last1=La Niece|first1=Susan|title=Gold|date=2009|publisher=The British Museum Press|isbn=978-0-7141-5076-5|page=20|url=|language=en}}</ref> Box with scene depicting Roman hero Gaius Mucius Scaevola before the Etruscan king Lars Porsena MET DP170836 (cropped).jpg|[[Rococo]] box, by [[George Michael Moser]], 1741, gold, Metropolitan Museum of Art Jean Joseph de Saint-Germain - Candelabrum - 1946.81 - Cleveland Museum of Art.tif|Rococo candelabrum, by [[Jean Joseph de Saint-Germain]], {{circa}}1750, gilt bronze, Cleveland Museum of Art Tabatière Minerve, Mercure, Pégase (Louvre, OA 2121).jpg|Rococo snuff box with [[Minerva]], by [[Jean-Malquis Lequin]], 1750–1752, gold and painted enamel, Louvre<ref>{{cite web|url=https://collections.louvre.fr/en/ark:/53355/cl010111221|website=collections.louvre.fr|title=Tabatière|access-date=18 November 2023}}</ref> File:Tabatière J-Frémin (Louvre, OA 6857).jpg|[[Louis XVI style]] snuff box, by [[Jean Frémin]], 1763–1764, gold and painted enamel, Louvre<ref>{{cite web|url=https://collections.louvre.fr/en/ark:/53355/cl010099410|website=collections.louvre.fr|title=Tabatière ovale|access-date=18 November 2023}}</ref> File:Washstand (athénienne or lavabo) MET DP106594.jpg|[[Neoclassicism|Neoclassical]] washstand (athénienne or lavabo), 1800–1814, legs, base and shelf of yew wood, gilt bronze mounts, iron plate beneath shelf, Metropolitan Museum of Art File:Clock, French, circa 1835-1840, gilt and patinated bronze, inherited from Maurice Quentin Bauchart, 1911, inv. 17741, Museum of Decorative Arts, Paris.jpg|[[Gothic Revival decorative arts|Gothic Revival]] clock, unknown French maker, {{circa}}1835-1840, gilt and patinated bronze, [[Musée des Arts Décoratifs, Paris|Museum of Decorative Arts]], Paris File:Teapot, by Alphonse Debain, from Paris, 1900, gilt silver and ivory, inv. 2021.63.1 MAD Paris.jpg|[[Art Nouveau]] teapot, by [[Alphonse Debain]], gilt silver and ivory, Museum of Decorative Arts </gallery> === Etymology === [[File:Beowulf - gold.jpg|thumb|An early mention of gold in the ''[[Beowulf]]'']] ''Gold'' is [[cognate]] with similar words in many [[Germanic languages]], deriving via [[Proto-Germanic]] [[wikt:Appendix:Proto-Germanic/gulþą|*''gulþą'']] from [[Proto-Indo-European]] [[wikt:Appendix:Proto-Indo-European/ǵʰelh₃-|*''ǵʰelh₃-'']] {{gloss|to shine, to gleam; to be yellow or green}}.<ref>{{OEtymD|gold}}</ref><ref>Hesse, R W. (2007) [https://books.google.com/books?id=DIWEi5Hg93gC&pg=PA103 Jewelrymaking Through History: An Encyclopedia] {{Webarchive|url=https://web.archive.org/web/20221101113823/https://books.google.com/books?id=DIWEi5Hg93gC&pg=PA103 |date=1 November 2022 }}, Greenwood Publishing Group. {{ISBN|0313335079}}</ref> The symbol ''Au'' is from the [[Latin]] {{lang|la|[[:wikt:aurum|aurum]]}} {{gloss|gold}}.<ref>Notre Dame University [http://www.archives.nd.edu/cgi-bin/lookup.pl?stem=Aurum&ending= Latin Dictionary] {{Webarchive|url=https://web.archive.org/web/20160205123228/http://www.archives.nd.edu/cgi-bin/lookup.pl?stem=Aurum&ending= |date=5 February 2016 }} Retrieved 7 June 2012</ref> The Proto-Indo-European ancestor of ''aurum'' was ''*h₂é-h₂us-o-'', meaning {{gloss|glow}}. This word is derived from the same [[Root (linguistics)|root]] (Proto-Indo-European ''*h₂u̯es-'' {{gloss|to dawn}}) as [[wikt:Appendix:Proto-Indo-European/h₂éwsōs|''*h₂éu̯sōs'']], the ancestor of the Latin word {{lang|la|[[aurora]]}} {{gloss|dawn}}.<ref>{{cite book |last=de Vaan |first=Michel |title=Etymological Dictionary of Latin and the other Italic languages |date=2008 |publisher=Brill |location=Leiden: Boston |isbn=978-90-04-16797-1 |page=63}}</ref> This etymological relationship is presumably behind the frequent claim in scientific publications that {{lang|la|aurum}} meant {{gloss|shining dawn}}.<ref name="Brathwaite">Christie, A and Brathwaite, R. (Last updated 2 November 2011) [https://web.archive.org/web/20130208092020/http://www.nzpam.govt.nz/cms/pdf-library/minerals/publications/Commodity%20Reports/report14_gold.pdf Mineral Commodity Report 14 — Gold], Institute of geological and Nuclear sciences Ltd – Retrieved 7 June 2012</ref> === Culture === {{anchor|Cultural history}} [[File:Jewelry and clothing ornaments.jpg|thumb|[[Arts in the Philippines|Gold crafts from the Philippines]] prior to Western contact]] In popular culture gold is a high standard of excellence, often used in awards.<ref name="martin08" /> Great achievements are frequently rewarded with gold, in the form of [[gold medal]]s, gold [[trophy|trophies]] and other decorations. Winners of athletic events and other graded competitions are usually awarded a gold medal. Many awards such as the [[Nobel Prize]] are made from gold as well. Other award statues and prizes are depicted in gold or are [[gold plated]] (such as the [[Academy Awards]], the [[Golden Globe Awards]], the [[Emmy Awards]], the [[Palme d'Or]], and the [[British Academy Film Awards]]).<ref>H. G. Bachmann, ''The lure of gold : an artistic and cultural history'' (2006).</ref> [[Aristotle]] in his [[Aristotelian ethics|ethics]] used gold symbolism when referring to what is now known as the [[golden mean (philosophy)|golden mean]]. Similarly, gold is associated with perfect or divine principles, such as in the case of the [[golden ratio]] and the [[golden rule]]. Gold is further associated with the wisdom of aging and fruition. The fiftieth [[wedding anniversary]] is golden. A person's most valued or most successful latter years are sometimes considered "golden years". The height of a civilization is referred to as a [[golden age (metaphor)|golden age]].<ref>Lubna Umar and Sarwet Rasul, "Critical Metaphor Analysis: Nawaz Sharif and the Myth of a Golden Time" ''NUML Journal of Critical Inquiry'' 15#2, (Dec 2017): 78–102.</ref> ====Religion==== [[File:Filippine, provincia di agusan, immagine hindu, statuetta in oro massiccio, xiii secolo.jpg|thumb|The [[Agusan image]], depicting a deity from northeast [[Mindanao]]]] The first known prehistoric human usages of gold were [[Prehistoric religion|religious]] in nature.<ref>{{Cite web |last=Lioudis |first=Nick |date=30 April 2023 |title=What Is the Gold Standard? Advantages, Alternatives, and History |url=https://www.investopedia.com/ask/answers/09/gold-standard.asp |access-date=21 September 2023 |website=[[Investopedia]] |language=en}}</ref> In some forms of Christianity and Judaism, gold has been associated both with the sacred and evil. In the [[Book of Exodus]], the [[Golden Calf]] is a symbol of [[idolatry]], while in the [[Book of Genesis]], [[Abraham]] was said to be rich in gold and silver, and Moses was instructed to cover the [[Mercy Seat]] of [[Ark of the Covenant|the Ark of the Covenant]] with pure gold. In [[Eastern Christianity|Byzantine]] [[icon]]ography the [[Halo (religious iconography)|halos]] of Christ, [[Virgin Mary]] and the saints are often golden.<ref>{{cite journal | last1 = Alborn | first1 = Timothy | year = 2017 | title = The Greatest Metaphor Ever Mixed: Gold in the British Bible, 1750–1850 | url = https://academicworks.cuny.edu/le_pubs/184| journal = Journal of the History of Ideas | volume = 78 | issue = 3| pages = 427–447 | doi = 10.1353/jhi.2017.0024 | pmid = 28757488 | s2cid = 27312741 }}</ref> In [[Islam]],<ref name="moors-etnofoor">{{cite journal |last1=Moors |first1=Annelies |title=Wearing gold, owning gold: the multiple meanings of gold jewelry |journal=Etnofoor |date=2013 |volume=25 |issue=1 |pages=78–89 |oclc=858949147|issn=0921-5158}}</ref> gold (along with [[silk]])<ref name="boulanouar-otago">{{cite thesis |last1=Boulanouar |first1=Aisha Wood |url=http://hdl.handle.net/10523/1748|title=Myths and Reality: Meaning in Moroccan Muslim Women's Dress |date=2011 |publisher=University of Otago |hdl=10523/1748 |type=Thesis, Doctor of Philosophy|citeseerx=10.1.1.832.2031 }}</ref><ref name="poonai-islamic-clothing">{{cite web |last1=Poonai |first1=Anand |title=Islamic Male Clothing |url=https://eportfolios.macaulay.cuny.edu/whatwewear/men/ |website=Who We Are & What We Wear |access-date=17 June 2020 |date=2015}}</ref> is often cited as being forbidden for men to wear.<ref name="aziz-hijab">{{cite journal |last1=Aziz |first1=Rookhsana |url=http://hdl.handle.net/10500/4888 |title=Hijab – The Islamic Dress Code: Its historical development, evidence from sacred sources and views of selected Muslim scholars |date=November 2010 |publisher=University of South Africa|journal=UNISA EDT (Electronic Theses and Dissertations)|hdl=10500/4888 |type=Thesis, Master of Arts|citeseerx=10.1.1.873.8651 }}</ref> [[Abu Bakr al-Jazaeri]], quoting a [[hadith]], said that "[t]he wearing of silk and gold are forbidden on the males of my nation, and they are lawful to their women".<ref name="byu-studies-toronto-umma">{{cite journal |last1=Toronto |first1=James A. |title=Many Voices, One ''Umma'': Sociopolitical Debate in the Muslim Community |journal=BYU Studies Quarterly |date=1 October 2001 |volume=40 |issue=4 |pages=29–50 |url=https://scholarsarchive.byu.edu/byusq/vol40/iss4/4}}</ref> This, however, has not been enforced consistently throughout history, e.g. in the Ottoman Empire.<ref name="jirousek-clothing">{{cite web |last1=Jirousek |first1=Charlotte |title=Islamic Clothing |url=http://char.txa.cornell.edu/islamicclothes.htm |publisher=Encyclopedia of Islam |access-date=17 June 2020 |date=2004}}</ref> Further, small gold accents on clothing, such as in [[embroidery]], may be permitted.<ref name="omar-dress">{{cite journal |last1=Omar |first1=Sara |title=Dress |journal=The Encyclopedia of Islam and Law, Oxford Islamic Studies Online |date=28 March 2014 |url=https://www.oxfordislamicstudies.com/article/opr/t349/e0040 }} {{Dead link|date=December 2021 |bot=InternetArchiveBot |fix-attempted=yes }}</ref> In [[ancient Greek religion]] and [[Greek mythology|mythology]], [[Theia]] was seen as the goddess of gold, silver and other [[Gemstone|gemstones]].<ref>{{cite book | page = [https://books.google.com/books?id=c7cNB-JaZA8C&pg=PT153 153] | last1 = Daly | last2 = Rengel | title = Greek and Roman Mythology, A to Z | first1 = Kathleen N. | first2 = Marian | publisher = Chelsea House Publishers | date = 1992 | isbn = 978-1-60413-412-4}}</ref> According to [[Christopher Columbus]], those who had something of gold were in possession of something of great value on Earth and a substance to even help souls to paradise.<ref>{{cite book |last=Bernstein |first=Peter L. |url=https://books.google.com/books?id=dIYmHiYhDu8C |title=The Power of Gold: The History of an Obsession |date=2004 |publisher=John Wiley & Sons |isbn=978-0-471-43659-1 |page=1}}</ref> [[Wedding ring]]s are typically made of gold. It is long lasting and unaffected by the passage of time and may aid in the ring symbolism of eternal vows before God and the perfection the marriage signifies. In [[Eastern Orthodox Church|Orthodox Christian]] wedding ceremonies, the wedded couple is adorned with a golden crown (though some opt for wreaths, instead) during the ceremony, an amalgamation of symbolic rites.{{Explain|reason=Is it a single crown and where does the amalgamation come from?|date=September 2023}} On 24 August 2020, [[Israel]]i archaeologists discovered a trove of early [[Islam]]ic gold coins near the central city of [[Yavne]]. Analysis of the extremely rare collection of 425 gold coins indicated that they were from the late 9th century. Dating to around 1,100 years back, the gold coins were from the [[Abbasid Caliphate]].<ref>{{cite web|url=https://apnews.com/5a35414a3fdcdf42c68a274b69595750|title=Israeli dig unearths large trove of early Islamic gold coins|access-date=24 August 2020|website=Associated Press|date=24 August 2020 }}</ref> == Production == {{Main|List of countries by gold production}} [[File:Gold - world production trend.svg|thumb|lang=en|Time trend of gold production|link=File:Gold_-_world_production_trend.svg%3Flang=en]] According to the [[United States Geological Survey]] in 2016, about {{convert|5,726,000,000|ozt|t}} of gold has been accounted for, of which 85% remains in active use.<ref>{{cite report |first1=John L. |last1=Munteen |first2=David A. |last2=Davis |first3=Bridget |last3=Ayling |date=2017 |title=The Nevada Mineral Industry 2016 |url=http://epubs.nsla.nv.gov/statepubs/epubs/210988-2016.pdf |publisher=University of Nevada, Reno |access-date=9 February 2019 |oclc=1061602920 |archive-url=https://web.archive.org/web/20190209232131/http://epubs.nsla.nv.gov/statepubs/epubs/210988-2016.pdf |archive-date=9 February 2019 |url-status=dead }}</ref> === Mining and prospecting === {{Main|Gold mining|Gold prospecting}} [[File:Miner underground at Pumsaint gold mine (1294028).jpg|thumb|left|A miner underground at [[Pumsaint]] gold mine, [[Wales]]; {{Circa|1938}}.]] [[File:Grasberg mine.jpg|upright=1|thumb|[[Grasberg mine]], Indonesia is the world's largest gold mine.]] Since the 1880s, South Africa has been the source of a large proportion of the world's gold supply, and about 22% of the gold presently accounted is from [[South Africa]]. Production in 1970 accounted for 79% of the world supply, about 1,480 tonnes. In 2007 [[China]] (with 276 tonnes) overtook South Africa as the world's largest gold producer, the first time since 1905 that South Africa had not been the largest.<ref>{{cite web |last=Mandaro |first=Laura |url=http://www.marketwatch.com/story/china-now-worlds-largest-gold-producer-foreign-miners-at-door |title=China now world's largest gold producer; foreign miners at door |website=[[MarketWatch]] |date=17 January 2008 |access-date=5 April 2009}}</ref> In 2020, [[Gold mining in China|China]] was the world's leading gold-mining country, followed in order by Russia, Australia, the United States, Canada, and Ghana.<ref name="production"/> [[File:Gold 30g for a 860kg rock.jpg|thumb|left|Relative sizes of an {{cvt|860|kg|adj=on}} block of gold ore and the {{cvt|30|g|ozt}} of gold that can be extracted from it, [[Toi gold mine]], [[Japan]].]] In South America, the controversial project [[Pascua Lama]] aims at exploitation of rich fields in the high mountains of [[Atacama Desert]], at the border between [[Chile]] and [[Argentina]]. It has been estimated that up to one-quarter of the yearly global gold production originates from artisanal or small scale mining.<ref>{{cite web |url=https://www.iisd.org/publications/global-trends-artisanal-and-small-scale-mining-asm-review-key-numbers-and-issues |last1=Fritz |first1=Morgane |last2=McQuilken |first2=James |last3=Collins |first3=Nina |last4=Weldegiorgis |first4=Fitsum |title=Global Trends in Artisanal and Small-Scale Mining (ASM): A review of key numbers and issues |via=Intergovernmental Forum on Mining, Minerals, Metals and Sustainable Development |format=PDF |type=Report |publisher=International Institute for Sustainable Development |location=Winnipeg Canada |date=January 2018 |access-date=24 February 2021}}</ref><ref>{{cite web |website=reuters.com |url=https://www.reuters.com/article/us-gold-mining-artisanal-explainer/what-is-artisanal-gold-and-why-is-it-booming-idUSKBN1ZE0YU |title=What is artisanal gold and why is it booming? |publisher=[[Reuters]] |date=15 January 2020 |access-date=24 February 2021 }}</ref><ref>{{Cite web |title=Removal of Barriers to the Abatement of Global Mercury Pollution from Artisanal Gold Mining |url=http://www.unido.org/fileadmin/import/10644_CHRISTIANtext.3.pdf |last=Beinhoff |first=Christian |access-date=29 December 2014 |url-status=dead |archive-url=https://web.archive.org/web/20160126032505/http://www.unido.org/fileadmin/import/10644_CHRISTIANtext.3.pdf |type=Report |archive-date=26 January 2016}}</ref> The city of [[Johannesburg]] located in South Africa was founded as a result of the [[Witwatersrand Gold Rush]] which resulted in the discovery of some of the largest natural gold deposits in recorded history. The gold fields are confined to the northern and north-western edges of the [[Witwatersrand basin]], which is a {{cvt|5|-|7|km|adj=on}} thick layer of [[archean]] rocks located, in most places, deep under the [[Free State (South African province)|Free State]], [[Gauteng]] and surrounding provinces.<ref name="Truswell">Truswell, J.F. (1977). ''The Geological Evolution of South Africa''. pp. 21–28. Purnell, Cape Town. {{ISBN|9780360002906}}</ref> These Witwatersrand rocks are exposed at the surface on the [[Witwatersrand]], in and around Johannesburg, but also in isolated patches to the south-east and south-west of Johannesburg, as well as in an arc around the [[Vredefort Dome]] which lies close to the center of the Witwatersrand basin.<ref name="McCarthy" /><ref name="Truswell" /> From these surface exposures the basin [[strike and dip|dips]] extensively, requiring some of the mining to occur at depths of nearly {{cvt|4000|m}}, making them, especially the [[Savuka Mine|Savuka]] and [[TauTona]] mines to the south-west of Johannesburg, the deepest mines on earth. The gold is found only in six areas where [[archean]] rivers from the north and north-west formed extensive pebbly [[Braided river]] deltas before draining into the "Witwatersrand sea" where the rest of the Witwatersrand sediments were deposited.<ref name="Truswell" /> The [[Second Boer War]] of 1899–1901 between the [[British Empire]] and the [[Afrikaner]] [[Boer]]s was at least partly over the rights of miners and possession of the gold wealth in South Africa. [[File:Kullanhuuhdontaa Ivalossa.jpg|thumb|Gold prospecting at the [[Ivalo River]] in the [[Lapland (Finland)|Finnish Lapland]] in 1898]] During the 19th century, [[gold rush]]es occurred whenever large gold deposits were discovered. The first documented discovery of gold in the United States was at the [[Reed Gold Mine]] near Georgeville, North Carolina in 1803.<ref>{{cite web |url=http://www.nchistoricsites.org/Reed/reed.htm |archive-url=https://web.archive.org/web/20120115012324/http://www.nchistoricsites.org/Reed/reed.htm |url-status=dead |archive-date=15 January 2012 |title=Reed Gold Mine State Historic Site |last=Moore |first=Mark A. |date=2006 |publisher=North Carolina Office of Archives and History |access-date=13 December 2008}}</ref> The first major gold strike in the United States occurred in a small north Georgia town called [[Dahlonega, Georgia|Dahlonega]].<ref>{{cite web |title=Road to adventure |publisher=Georgia Magazine |last=Garvey |first=Jane A. |url=http://www.georgiamagazine.org/archives_view.asp?mon=7&yr=2006&ID=1344 |date=2006 |access-date=23 January 2007 |url-status=dead |archive-url=https://web.archive.org/web/20070302212304/http://www.georgiamagazine.org/archives_view.asp?mon=7&yr=2006&ID=1344 |archive-date=2 March 2007 }}</ref> Further gold rushes occurred in [[California Gold Rush|California]], [[Pike's Peak Gold Rush|Colorado]], the [[Black Hills Gold Rush|Black Hills]], [[Central Otago Gold Rush|Otago]] in New Zealand, a number of locations across [[Australian gold rushes|Australia]], [[Witwatersrand Gold Rush|Witwatersrand]] in South Africa, and the [[Klondike Gold Rush|Klondike]] in Canada. [[Grasberg mine]] located in [[Papua (province)|Papua]], [[Indonesia]] is the largest [[gold mining|gold mine]] in the world.<ref>{{cite web|title=Grasberg Open Pit, Indonesia|url=http://www.mining-technology.com/projects/grasbergopenpit|website=Mining Technology|access-date=16 October 2017}}</ref> === Extraction and refining === {{Main|Gold extraction}} [[Image:Gold nuggets from Arizona.jpg|thumb|left|Gold Nuggets found in [[Arizona]].]] [[Gold extraction]] is most economical in large, easily mined deposits. Ore grades as little as 0.5 parts per million (ppm) can be economical. Typical ore grades in [[open-pit mining|open-pit]] mines are 1–5 ppm; ore grades in underground or [[Underground mining (hard rock)|hard rock]] mines are usually at least 3 ppm. Because ore grades of 30 ppm are usually needed before gold is visible to the naked eye, in most gold mines the gold is invisible. The average gold mining and extraction costs were about $317 per troy ounce in 2007, but these can vary widely depending on mining type and ore quality; global mine production amounted to 2,471.1 tonnes.<ref>{{Cite news |last=O'Connell |first=Rhona |date=13 April 2007 |title=Gold mine production costs up by 17% in 2006 while output fell |url=http://www.mineweb.net/mineweb/view/mineweb/en/page33?oid=19485&sn=Detail |url-status=dead |archive-url=https://web.archive.org/web/20141006084904/http://www.mineweb.net/mineweb/view/mineweb/en/page33?oid=19485&sn=Detail |archive-date=6 October 2014}}</ref> After initial production, gold is often subsequently refined industrially by the [[Wohlwill process]] which is based on [[electrolysis]] or by the [[Miller process]], that is chlorination in the melt. The Wohlwill process results in higher purity, but is more complex and is only applied in small-scale installations.<ref>{{Cite book |last=Noyes |first=Robert |url=https://books.google.com/books?id=__lqGczo9TwC&pg=PA342 |page=342 |title=Pollution prevention technology handbook |publisher=William Andrew |date=1993 |isbn=978-0-8155-1311-7}}</ref><ref>{{Cite book |last1=Pletcher |first1=Derek |first2=Frank |last2=Walsh |url=https://books.google.com/books?id=E_u9ARrm37oC&pg=PA244 |page=244 |title=Industrial electrochemistry |name-list-style=amp |publisher=Springer |date=1990 |isbn=978-0-412-30410-1}}</ref> Other methods of assaying and purifying smaller amounts of gold include parting and inquartation as well as [[cupellation]], or refining methods based on the dissolution of gold in aqua regia.<ref>{{cite book |last1=Marczenko |first1=Zygmunt |last2=Balcerzak |first2=María |url=https://books.google.com/books?id=0NE1KjVISyAC&pg=PA210 |page=210 |title=Separation, preconcentration, and spectrophotometry in inorganic analysis |name-list-style=amp |publisher=Elsevier |date=2000 |isbn=978-0-444-50524-8}}</ref> ===Recycling=== In 1997, recycled gold accounted for approximately 20% of the 2700 tons of gold supplied to the market.<ref>{{cite book |doi=10.1002/14356007.a12_499 |chapter=Gold, Gold Alloys, and Gold Compounds |title=Ullmann's Encyclopedia of Industrial Chemistry |year=2000 |last1=Renner |first1=Hermann |last2=Schlamp |first2=Günther |last3=Hollmann |first3=Dieter |last4=Lüschow |first4=Hans Martin |last5=Tews |first5=Peter |last6=Rothaut |first6=Josef |last7=Dermann |first7=Klaus |last8=Knödler |first8=Alfons |last9=Hecht |first9=Christian |last10=Schlott |first10=Martin |last11=Drieselmann |first11=Ralf |last12=Peter |first12=Catrin |last13=Schiele |first13=Rainer |isbn=3527306730 }}</ref> Jewelry companies such as Generation Collection and computer companies including [[Dell]] conduct recycling<ref>{{cite news|last=Paton|first=Elizabeth|date=23 April 2021|title=Does Recycled Gold Herald a Greener Future for Jewelry?|language=en-US|work=The New York Times|url=https://www.nytimes.com/2021/04/23/fashion/jewelry-recycled-gold.html |archive-url=https://ghostarchive.org/archive/20211228/https://www.nytimes.com/2021/04/23/fashion/jewelry-recycled-gold.html |archive-date=28 December 2021 |url-access=limited|access-date=17 May 2021|issn=0362-4331}}{{cbignore}}</ref> As of 2020, the amount of [[carbon dioxide]] {{chem2|CO2}} produced in mining a kilogram of gold is 16 tonnes, while recycling a kilogram of gold produces 53 kilograms of {{chem2|CO2}} equivalent. Approximately 30 percent of the global gold supply is recycled and not mined as of 2020.<ref>{{cite news |last=Baraniuk |first=Chris |title=Why it's getting harder to mine gold |url=https://www.bbc.com/future/article/20201026-why-its-getting-harder-to-mine-gold |publisher=[[BBC]] |date=27 October 2020 |access-date=29 October 2020}}</ref> === Consumption === {{update|date=May 2022}} {| style=" text-align:right;float:right" class="wikitable sortable" |+ Gold jewelry consumption by country (in tonnes)<ref>{{cite news |url=http://www.forexyard.com/en/news/Gold-jewellery-consumption-by-country-2011-02-28T130619Z-FACTBOX |archive-url=https://web.archive.org/web/20120112003914/http://www.forexyard.com/en/news/Gold-jewellery-consumption-by-country-2011-02-28T130619Z-FACTBOX |archive-date=12 January 2012 |title=Gold jewellery consumption by country |date=28 February 2011 |agency=Reuters}}</ref><ref>{{cite web |url=http://www.gold.org/investment/research/regular_reports/gold_demand_trends/ |title=Gold Demand Trends | Investment | World Gold Council |publisher=Gold.org |access-date=12 September 2013}}</ref><ref>{{cite web |url=http://www.gold.org/investment/research/regular_reports/gold_demand_trends/ |title=Gold Demand Trends |date=12 November 2015}}</ref> |- ! Country !! 2009 !! 2010 !! 2011 !! 2012 !! 2013 |- | align=left|{{flag|India}} || 442.37 || 745.70 || 986.3 || 864 || 974 |- | align=left|{{flag|China}} || 376.96 || 428.00 || 921.5 || 817.5 || 1120.1 |- | align=left|{{flag|United States}} || 150.28 || 128.61 || 199.5 || 161 || 190 |- | align=left|{{flag|Turkey}} || 75.16 || 74.07 || 143 || 118 || 175.2 |- | align=left|{{flag|Saudi Arabia}} || 77.75 || 72.95 || 69.1 ||58.5 || 72.2 |- | align=left|{{flag|Russia}} || 60.12 || 67.50 || 76.7 || 81.9 || 73.3 |- | align=left|{{flag|United Arab Emirates}} || 67.60 || 63.37 || 60.9 ||58.1 || 77.1 |- | align=left|{{flag|Egypt}} || 56.68 || 53.43 || 36 ||47.8 || 57.3 |- | align=left|{{flag|Indonesia}} || 41.00 || 32.75 || 55 || 52.3 || 68 |- | align=left|{{flag|United Kingdom}} || 31.75 || 27.35 || 22.6 || 21.1 || 23.4 |- | align=left|Other Persian Gulf Countries || 24.10 || 21.97 || 22 || 19.9 || 24.6 |- | align=left|{{flag|Japan}} || 21.85 || 18.50 || −30.1 || 7.6 || 21.3 |- | align=left|{{flag|South Korea}} || 18.83 || 15.87 || 15.5 ||12.1 || 17.5 |- | align=left|{{flag|Vietnam}} || 15.08 || 14.36 || 100.8 || 77 || 92.2 |- | align=left|{{flag|Thailand}} || 7.33 || 6.28 || 107.4 || 80.9 || 140.1 |- | align=left|'''Total''' || '''1466.86''' || '''1770.71''' || '''2786.12 ''' || '''2477.7''' || '''3126.1 ''' |- | align=left|''Other Countries'' || ''251.6'' || ''254.0'' || ''390.4'' || ''393.5'' || ''450.7'' |- | align=left|'''World Total''' || '''1718.46''' || '''2024.71''' || '''3176.52'''|| '''2871.2''' || '''3576.8''' |} The consumption of gold produced in the world is about 50% in jewelry, 40% in investments, and 10% in industry.<ref name="oil-price.com-worlds-gold-consumption 2011" /><ref>{{cite web |url=http://www.usdebtclock.org/gold-demand-by-country.html |title=Country wise gold demand |access-date=2 October 2015}}</ref> According to the [[World Gold Council]], China was the world's largest single consumer of gold in 2013, overtaking India.<ref>{{cite web |last=Harjani |first=Ansuya |url=https://www.cnbc.com/id/101422278# |title=It's official: China overtakes India as top consumer of gold |publisher=[[CNBC]] |date=18 February 2014 |access-date=2 July 2014}}</ref> === Pollution === {{further|Mercury cycle|International Cyanide Management Code}} Gold production is associated with contribution to hazardous [[Environmental effects of mining|pollution]].<ref>{{cite journal |last2=Marikar |first2=Fouzul |last1=Abdul-Wahab |title=The environmental impact of gold mines: pollution by heavy metals |journal=Central European Journal of Engineering |volume=2 |issue=2 |pages=304–313 |date=24 October 2011 |bibcode=2012CEJE....2..304A|s2cid=3916088 |doi=10.2478/s13531-011-0052-3|doi-access=free }}</ref> Low-grade gold ore may contain less than one [[Parts per million|ppm]] gold metal; such ore is [[Milling (grinding)|ground]] and mixed with [[sodium cyanide]] to dissolve the gold. Cyanide is a highly poisonous chemical, which can kill living creatures when exposed in minute quantities. Many [[List of gold mining disasters|cyanide spills]]<ref>[http://www.deseretnews.com/article/810435/Cyanide-spill-compared-to-Chernobyls---N-disaster.html Cyanide spills from gold mine compared to Chernobyl's nuclear disaster] {{webarchive |url=https://web.archive.org/web/20180714135300/https://www.deseretnews.com/article/810435/Cyanide-spill-compared-to-Chernobyls---N-disaster.html |date=14 July 2018}}. Deseretnews.com (14 February 2000). Retrieved on 4 May 2012.</ref> from gold mines have occurred in both developed and developing countries which killed aquatic life in long stretches of affected rivers. Environmentalists consider these events major environmental disasters.<ref>[http://news.bbc.co.uk/2/hi/europe/642880.stm Death of a river] {{Webarchive|url=https://web.archive.org/web/20090109134649/http://news.bbc.co.uk/2/hi/europe/642880.stm |date=9 January 2009 }}. BBC News (15 February 2000). Retrieved on 4 May 2012.</ref><ref>[http://www.abc.net.au/am/stories/s98890.htm Cyanide spill second only to Chernobyl] {{Webarchive|url=https://web.archive.org/web/20170525072149/http://www.abc.net.au/am/stories/s98890.htm |date=25 May 2017 }}. Abc.net.au. 11 February 2000. Retrieved on 4 May 2012.</ref> Up to thirty tons of used ore can be dumped as waste for producing one troy ounce of gold.<ref name="NYT">[https://www.nytimes.com/2005/10/24/international/24GOLD.html Behind gold's glitter, torn lands and pointed questions] {{Webarchive|url=https://web.archive.org/web/20150408113857/http://www.nytimes.com/2005/10/24/international/24GOLD.html |date=8 April 2015 }}, ''The New York Times'', 24 October 2005</ref> Gold ore dumps are the source of many heavy elements such as cadmium, lead, zinc, copper, [[arsenic]], [[selenium]] and mercury. When sulfide-bearing minerals in these ore dumps are exposed to air and water, the sulfide transforms into [[sulfuric acid]] which in turn dissolves these heavy metals facilitating their passage into surface water and ground water. This process is called [[acid mine drainage]]. These gold ore dumps contain long-term, highly hazardous waste.<ref name="NYT" /> It was once common to use mercury to recover gold from ore, but today the use of mercury is largely limited to small-scale individual miners.<ref>{{cite web |url=http://www.worstpolluted.org/files/FileUpload/files/WWPP_2012.pdf |archive-url=https://web.archive.org/web/20150402130613/http://www.worstpolluted.org/files/FileUpload/files/WWPP_2012.pdf |archive-date=2 April 2015 |url-status=live |title=Pollution from Artisanal Gold Mining, Blacksmith Institute Report 2012 |access-date=22 September 2015}}</ref> Minute quantities of mercury compounds can reach water bodies, causing heavy metal contamination. Mercury can then enter into the human food chain in the form of [[methylmercury]]. [[Mercury poisoning]] in humans causes incurable brain function damage and severe retardation.<ref>{{cite web|last=Wroblewski|first=William|date=12 January 2022|title='Babies here are born sick': are Bolivia's gold mines poisoning its indigenous people?|url=https://www.theguardian.com/global-development/2022/jan/12/babies-here-are-born-sick-are-bolivias-gold-mines-poisoning-its-indigenous-people|access-date=12 January 2022|website=The Guardian|language=en}}</ref> Gold extraction is also a highly energy-intensive industry, extracting ore from deep mines and grinding the large quantity of ore for further chemical extraction requires nearly 25 [[Kilowatt-hour|kWh]] of electricity per gram of gold produced.<ref>{{cite journal |doi=10.1016/j.jclepro.2012.01.042 |title=Using life cycle assessment to evaluate some environmental impacts of gold |date=2012 |last1=Norgate |first1=Terry |last2=Haque |first2=Nawshad |journal=Journal of Cleaner Production |volume=29–30 |pages=53–63}}</ref> == Monetary use == {{Further|History of money}} [[File:Two 20kr gold coins.png|thumb|right|Two golden 20 kr coins from the [[Scandinavian Monetary Union]], which was based on a [[gold standard]]. The coin to the left is [[Sweden|Swedish]] and the right one is [[Denmark|Danish]].]] Gold has been [[History of money|widely used]] throughout the world as [[money]],<ref>{{Cite book |url=https://books.google.com/books?id=Hx-AU99lho4C&pg=PA192 |title=Man, Economy, and State, Scholar's Edition |last=Rothbard |first=Murray N. |date=2009 |publisher=Ludwig von Mises Institute |isbn=978-1-933550-99-2}}</ref> for efficient indirect exchange (versus [[barter]]), and to store wealth in [[hoard]]s. For exchange purposes, [[Mint (coin)|mints]] produce standardized [[bullion|gold bullion]] [[coins]], [[gold bar|bars]] and [[Good delivery|other units]] of fixed weight and purity. The first known coins containing gold were struck in Lydia, Asia Minor, around 600 BC.<ref name="lion">{{cite web |url=http://rg.ancients.info/lion/article.html |title=A Case for the World's Oldest Coin: Lydian Lion |publisher=Rg.ancients.info |date=2 October 2003 |access-date=27 October 2013}}</ref> The ''[[talent (measurement)|talent]]'' coin of gold in use during the periods of Grecian history both before and during the time of the life of Homer weighed between 8.42 and 8.75 grams.<ref>{{cite book |last=Seltman |first=C. T. |url=https://books.google.com/books?id=Uas8AAAAIAAJ&pg=PA116 |title=Athens, Its History and Coinage Before the Persian Invasion |access-date=4 June 2012 |isbn=978-0-87184-308-1 |date=1924}}</ref> From an earlier preference in using silver, European economies re-established the minting of gold as coinage during the thirteenth and fourteenth centuries.<ref name="Postan & Miller">{{cite book |last1=Postan |first1=M. M. |last2=Miller |first2=E. |url=https://books.google.com/books?id=wSia_4PpeqQC&pg=PR1 |title=The Cambridge Economic History of Europe: Trade and industry in the Middle Ages |publisher=Cambridge University Press, 28 August 1987 |isbn=978-0-521-08709-4 |date=1967}}</ref> [[Real bills doctrine|Bills]] (that mature into gold coin) and [[gold certificates]] (convertible into gold coin at the issuing bank) added to the circulating stock of [[gold standard]] money in most 19th century industrial economies. In preparation for [[World War I]] the warring nations moved to fractional gold standards, inflating their currencies to finance the war effort. Post-war, the victorious countries, most notably Britain, gradually restored gold-convertibility, but international flows of gold via bills of exchange remained embargoed; international shipments were made exclusively for bilateral trades or to pay war reparations. After [[World War II]] gold was replaced by a system of nominally [[convertible currency|convertible currencies]] related by fixed exchange rates following the [[Bretton Woods system]]. [[Gold standard]]s and the direct convertibility of currencies to gold have been abandoned by world governments, led in 1971 by the United States' refusal to redeem its dollars in gold. [[Fiat currency]] now fills most monetary roles. [[Switzerland]] was the last country to tie its currency to gold; this was ended by a referendum in 1999.<ref>{{cite news |url=https://www.nytimes.com/1999/04/19/world/swiss-narrowly-vote-to-drop-gold-standard.html |work=The New York Times |title=Swiss Narrowly Vote to Drop Gold Standard |date=19 April 1999 |access-date=1 July 2022}}</ref> Central banks continue to keep a portion of their liquid reserves as gold in some form, and metals exchanges such as the [[London Bullion Market Association]] still clear transactions denominated in gold, including future delivery contracts. Today, [[gold mining]] output is declining.<ref>{{cite web |last=King |first=Byron |url=http://goldnews.bullionvault.com/gold_mine_production_072020092 |archive-url=http://arquivo.pt/wayback/20160515213855/http://goldnews.bullionvault.com/gold_mine_production_072020092 |archive-date=15 May 2016 |title=Gold mining decline |publisher=BullionVault.com |date=20 July 2009 |access-date=23 November 2009}}</ref> With the sharp growth of economies in the 20th century, and increasing foreign exchange, the world's [[gold reserve]]s and their trading market have become a small fraction of all markets and fixed exchange rates of currencies to gold have been replaced by floating prices for gold and gold [[Futures contract|future contract]]. Though the gold stock grows by only 1% or 2% per year, very little metal is irretrievably consumed. Inventory above ground would satisfy many decades of industrial and even artisan uses at current prices. The gold proportion ([[fineness]]) of alloys is measured by [[fineness#karat|karat]] (k). Pure gold (commercially termed ''fine'' gold) is designated as 24 karat, abbreviated 24k. English gold coins intended for circulation from 1526 into the 1930s were typically a standard 22k alloy called [[crown gold]],<ref>{{cite book |last1=Lawrence |first1=Thomas Edward |url=https://books.google.com/books?id=tu86AAAAIAAJ&pg=PA103 |page=103 |title=The Mint: A Day-book of the R.A.F. Depot Between August and December 1922, with Later Notes |date=1948}}</ref> for hardness (American gold coins for circulation after 1837 contain an alloy of 0.900 fine gold, or 21.6 kt).<ref>{{cite book |last=Tucker |first=George |url=https://archive.org/details/theorymoneyandb00tuckgoog |title=The theory of money and banks investigated |publisher=C. C. Little and J. Brown |date=1839}}</ref> Although the prices of some [[platinum]] group metals can be much higher, gold has long been considered the most desirable of [[precious metal]]s, and its value has been used as the standard for many [[currency|currencies]]. Gold has been used as a symbol for purity, value, royalty, and particularly roles that combine these properties. Gold as a sign of wealth and prestige was ridiculed by [[Thomas More]] in his treatise ''[[Utopia (More book)|Utopia]]''. On that imaginary island, gold is so abundant that it is used to make chains for slaves, tableware, and lavatory seats. When ambassadors from other countries arrive, dressed in ostentatious gold jewels and badges, the Utopians mistake them for menial servants, paying homage instead to the most modestly dressed of their party. The [[ISO 4217]] currency code of gold is XAU.<ref>{{cite web |url=http://www.iso.org/iso/home/standards/currency_codes.htm |title=Currency codes – ISO 4217 |publisher=International Organization for Standardization |access-date=25 December 2014}}</ref> Many holders of gold store it in form of [[bullion]] coins or [[gold bar|bars]] as a hedge against [[inflation]] or other economic disruptions, though its efficacy as such has been questioned; historically, it has not proven itself reliable as a hedging instrument.<ref>{{Cite web |url=https://medium.com/hedgehound/hedgehound-fridayfinance-on-hedging-inflation-with-gold-375f3ce09cfe |title=On hedging inflation with gold |last=Valenta |first=Philip |date=22 June 2018 |website=Medium|access-date=30 November 2018}}</ref> Modern [[bullion coin]]s for investment or collector purposes do not require good mechanical wear properties; they are typically fine gold at 24k, although the [[American Gold Eagle]] and the British [[Sovereign (British coin)|gold sovereign]] continue to be minted in 22k (0.92) metal in historical tradition, and the South African [[Krugerrand]], first released in 1967, is also 22k (0.92).<ref>{{cite web |url=http://www.americansilvereagletoday.com/the-ever-popular-krugerrand |archive-url=https://web.archive.org/web/20110203024339/http://www.americansilvereagletoday.com/the-ever-popular-krugerrand/ |archive-date=3 February 2011 |title=The Ever Popular Krugerrand |date=2010 |website=americansilvereagletoday.com |access-date=30 August 2011}}</ref> The ''special issue'' [[Canadian Gold Maple Leaf]] coin contains the highest purity gold of any [[bullion coin]], at 99.999% or 0.99999, while the ''popular issue'' Canadian Gold Maple Leaf coin has a purity of 99.99%. In 2006, the [[United States Mint]] began producing the [[American Buffalo (coin)|American Buffalo]] gold bullion coin with a purity of 99.99%. The [[Australia]]n Gold Kangaroos were first coined in 1986 as the [[Australian Gold Nugget]] but changed the reverse design in 1989. Other modern coins include the [[Austria]]n [[Vienna Philharmonic (coin)|Vienna Philharmonic]] bullion coin and the [[Chinese Gold Panda]].<ref>{{cite web |url=https://goldsilver.com/blog/what-are-the-different-purities-of-sovereign-gold-coins/ |title=What Are the Different Purities of Sovereign Gold Coins? |website=goldsilver.com |access-date=29 March 2021}}</ref> === Price === {{further|Gold as an investment}} [[File:Gold price in USD.png|thumb|upright=1.35|Gold price history in 1960–2020.]] Like other precious metals, gold is measured by [[troy weight]] and by grams. The proportion of gold in the alloy is measured by ''[[fineness#karat|karat]]'' (k), with 24 karat (24k) being pure gold (100%), and lower karat numbers proportionally less (18k = 75%). The purity of a [[gold bar]] or coin can also be expressed as a decimal figure ranging from 0 to 1, known as the [[fineness#millesimal_fineness|millesimal fineness]], such as 0.995 being nearly pure. The price of gold is determined through trading in the gold and [[derivative (finance)|derivatives]] markets, but a procedure known as the [[Gold Fixing]] in [[London]], originating in September 1919, provides a daily benchmark price to the industry. The afternoon fixing was introduced in 1968 to provide a price when US markets are open.<ref>{{cite book |last1=Warwick-Ching |first1=Tony |url=https://books.google.com/books?id=GrQQxVrtJ3sC&pg=PA26 |page=26 |title=The International Gold Trade |isbn=978-1-85573-072-4 |date=28 February 1993|publisher=Woodhead }}</ref> {{as of|2017|September|}}, gold was valued at around $42 per gram ($1,300 per troy ounce). === History === Historically gold [[Mint (coin)|coinage]] was widely used as currency; when [[paper money]] was introduced, it typically was a [[receipt]] redeemable for gold coin or [[bullion]]. In a [[monetary]] system known as the [[gold standard]], a certain [[weight]] of gold was given the name of a unit of currency. For a long period, the United States government set the value of the US dollar so that one [[troy ounce]] was equal to $20.67 ($0.665 per gram), but in 1934 the dollar was devalued to $35.00 per troy ounce ($0.889/g). By 1961, it was becoming hard to maintain this price, and [[London Gold Pool|a pool of US and European banks]] agreed to manipulate the market to prevent further [[devaluation|currency devaluation]] against increased gold demand.<ref>{{cite book |last1=Elwell |url=https://books.google.com/books?id=ztHyT2ew3QUC&pg=PA11 |pages=11–13 |title=Brief History of the Gold Standard (GS) in the United States |isbn=978-1-4379-8889-5 |first1=Craig K. |date=2011| publisher=DIANE }}</ref> The largest gold depository in the world is that of the [[Federal Reserve System|U.S. Federal Reserve Bank]] in [[New York City|New York]], which holds about 3%<ref name='ISAMPE 2006-11-22'>{{cite web |first2=Christian |last2=Perwass |url=http://sinai.apphy.u-fukui.ac.jp/gcj/publications/gold/gold.pdf |archive-url=https://web.archive.org/web/20120127152357/http://sinai.apphy.u-fukui.ac.jp/gcj/publications/gold/gold.pdf |archive-date=27 January 2012 |title=The hidden beauty of gold |access-date=10 May 2011 |last1=Hitzer |first1=Eckhard |date=22 November 2006 |website=Proceedings of the International Symposium on Advanced Mechanical and Power Engineering 2007 (ISAMPE 2007) between Pukyong National University (Korea), University of Fukui (Japan) and University of Shanghai for Science and Technology (China), 22–25 November 2006, hosted by the University of Fukui (Japan), pp. 157–167. (Figs 15,16,17,23 revised.)}}</ref> of the gold known to exist and accounted for today, as does the similarly laden [[United States Bullion Depository|U.S. Bullion Depository]] at [[Fort Knox]]. In 2005 the [[World Gold Council]] estimated total global gold supply to be 3,859 tonnes and demand to be 3,754 tonnes, giving a surplus of 105 tonnes.<ref>{{cite web |url=http://www.gold.org/value/stats/statistics/gold_demand/index.html |archive-url=https://web.archive.org/web/20060719111349/http://www.gold.org/value/stats/statistics/gold_demand/index.html |archive-date=19 July 2006 |title=World Gold Council > value > research & statistics > statistics > supply and demand statistics |access-date=22 July 2006}}</ref> After 15 August 1971 [[Nixon shock]], the price began to greatly increase,<ref>{{cite web |publisher=kitco |url=http://www.kitco.com/charts/historicalgold.html |title=historical charts:gold – 1833–1999 yearly averages |access-date=30 June 2012}}</ref> and between 1968 and 2000 the price of gold ranged widely, from a high of $850 per troy ounce ($27.33/g) on 21 January 1980, to a low of $252.90 per troy ounce ($8.13/g) on 21 June 1999 (London Gold Fixing).<ref>[http://kitco.com/LFgif/au75-pres.gif Kitco.com] {{Webarchive|url=https://web.archive.org/web/20180714081628/http://www.kitco.com/LFgif/au75-pres.gif |date=14 July 2018 }}, Gold – London PM Fix 1975 – present (GIF), Retrieved 22 July 2006.</ref> Prices increased rapidly from 2001, but the 1980 high was not exceeded until 3 January 2008, when a new maximum of $865.35 per [[troy weight|troy ounce]] was set.<ref name="LBMA statistics">{{cite web |url=http://www.lbma.org.uk/2008dailygold.htm |archive-url=https://web.archive.org/web/20090210035134/http://lbma.org.uk/2008dailygold.htm |archive-date=10 February 2009 |title=LBMA statistics |publisher=Lbma.org.uk |date=31 December 2008 |access-date=5 April 2009}}</ref> Another record price was set on 17 March 2008, at $1023.50 per troy ounce ($32.91/g).<ref name="LBMA statistics" /> On 2 December 2009, gold reached a new high closing at $1,217.23.<ref>{{cite news |url=http://news.bbc.co.uk/2/hi/business/8390779.stm |title=Gold hits yet another record high |work=BBC News |date=2 December 2009 |access-date=6 December 2009}}</ref> Gold further rallied hitting new highs in May 2010 after the European Union debt crisis prompted further purchase of gold as a safe asset.<ref>{{Cite news |title=PRECIOUS METALS: Comex Gold Hits All-Time High |newspaper=[[The Wall Street Journal]] |date=11 May 2012 |url=https://www.wsj.com/article/BT-CO-20100511-717954.html |access-date=4 August 2010}} {{dead link|date=June 2016|bot=medic}}{{cbignore|bot=medic}}</ref><ref>{{cite web |url=http://www.marketwatch.com/story/gold-prices-resume-rise-as-eu-plan-pondered-2010-05-11 |title=Gold futures hit closing record as investors fret rescue deal |last1=Gibson |first1=Kate |last2=Chang |first2=Sue |date=11 May 2010 |website=[[MarketWatch]] |access-date=4 August 2010}}</ref> On 1 March 2011, gold hit a new all-time high of $1432.57, based on [[Gold as an investment|investor]] concerns regarding ongoing [[Arab Spring|unrest]] in [[North Africa]] as well as in the [[Middle East]].<ref>{{cite news |url=https://www.reuters.com/article/markets-global-idUSN0115419520110301 |title=Gold hits record, oil jumps with Libya unrest |work=Reuters |date=1 March 2011 |access-date=1 March 2011 |first=Caroline |last=Valetkevitch |archive-date=15 October 2015 |archive-url=https://web.archive.org/web/20151015231151/http://www.reuters.com/article/2011/03/01/markets-global-idUSN0115419520110301 |url-status=live }}</ref> From April 2001 to August 2011, spot gold prices more than quintupled in value against the US dollar, hitting a new all-time high of $1,913.50 on 23 August 2011,<ref>{{cite news |url=https://www.bloomberg.com/news/2011-08-25/cash-gold-may-advance-after-dropping-most-in-18-months-as-shares-rebound.html |title=Gold Extends Biggest Decline in 18 Months After CME Raises Futures Margins |publisher=Bloomberg |date=23 August 2011 |access-date=24 February 2021 |first=Glenys |last=Sim |url-status=live |archive-url=https://web.archive.org/web/20140110002029/http://www.bloomberg.com/news/2011-08-25/cash-gold-may-advance-after-dropping-most-in-18-months-as-shares-rebound.html |archive-date=10 January 2014}}</ref> prompting speculation that the long [[secular bear market]] had ended and a [[bull market]] had returned.<ref>{{cite web |url=http://www.ameinfo.com/75511.html |archive-url=https://web.archive.org/web/20090421094351/http://www.ameinfo.com/75511.html |archive-date=21 April 2009 |title=Financial Planning{{!}}Gold starts 2006 well, but this is not a 25-year high! |publisher=Ameinfo.com|access-date=5 April 2009}}</ref> However, the price then began a slow decline towards $1200 per troy ounce in late 2014 and 2015. In August 2020, the gold price picked up to US$2060 per ounce after a total growth of 59% from August 2018 to October 2020, a period during which it outplaced the Nasdaq total return of 54%.<ref>{{cite web|url=https://www.efgbank.com/it/coronavirus/14-October-2020.html|date=14 October 2020 |title=Gold, monetary policy and the US dollar|first=GianLuigi |last=Mandruzzato|url-status=dead|archive-url=https://web.archive.org/web/20201106083115/https://www.efgbank.com/it/coronavirus/14-October-2020.html|archive-date=6 November 2020 }}</ref> Gold futures are traded on the COMEX exchange.<ref name="PortaraCQG">{{Cite web |title=Historical Gold Intraday Futures Data (GCA) |url=https://portaracqg.com/historical-futures-data/gold-intraday-data-gca/ |access-date=28 April 2022 |website=PortaraCQG |language=en-US}}</ref> These contacts are priced in USD per troy ounce (1 troy ounce = 31.1034768 grams).<ref>{{Cite web |title=Troy Ounce |url=https://www.investopedia.com/terms/t/troyounce.asp |access-date=28 April 2022 |website=Investopedia |language=en}}</ref> Below are the [[CQG]] contract specifications outlining the futures contracts: {| class="wikitable" |+Contract Specifications<ref name="PortaraCQG" /> !Gold (GCA) ! |- |Exchange: |COMEX |- |Sector: |Metal |- |Tick Size: |0.1 |- |Tick Value: |10 USD |- |BPV: |100 |- |Denomination: |USD |- |Decimal Place: |1 |} == Other applications == === Jewelry === [[File:MocheGoldNecklace.jpg|thumb|[[Moche (culture)|Moche]] gold necklace depicting feline heads. [[Larco Museum]] Collection, [[Lima, Peru]].]] [[File:Boule de Genève, ca. 1890.jpeg|thumb|A 21.5k yellow gold pendant [[watch]] so-called "[[Boule de Genève]]" (Geneva ball), {{Circa|1890}}.]] Because of the softness of pure (24k) gold, it is usually [[alloy]]ed with other metals for use in jewelry, altering its hardness and ductility, melting point, color and other properties. Alloys with lower [[fineness#Karat|karat rating]], typically 22k, 18k, 14k or 10k, contain higher percentages of copper, silver, palladium or other base metals in the alloy.<ref name="utilisegold">[https://web.archive.org/web/20080619061619/http://www.utilisegold.com/jewellery_technology/colours/colour_alloys/ Jewellery Alloys]. World Gold Council</ref><!--Is there a better ref?--> Nickel is toxic, and its release from nickel white gold is controlled by legislation in Europe.<ref name="utilisegold" /> Palladium-gold alloys are more expensive than those using nickel.<ref>{{Cite book |url=https://books.google.com/books?id=W_hTAAAAMAAJ |title=Professional goldsmithing: a contemporary guide to traditional jewelry techniques |last=Revere |first=Alan |date=1 May 1991 |publisher=Van Nostrand Reinhold |isbn=978-0-442-23898-8}}</ref> High-karat white gold alloys are more resistant to corrosion than are either pure silver or [[sterling silver]]. The Japanese craft of [[Mokume-gane]] exploits the color contrasts between laminated colored gold alloys to produce decorative wood-grain effects. By 2014, the gold jewelry industry was escalating despite a dip in gold prices. Demand in the first quarter of 2014 pushed turnover to $23.7 billion according to a [[World Gold Council]] report. Gold [[solder]] is used for joining the components of gold jewelry by high-temperature hard soldering or [[brazing]]. If the work is to be of [[hallmark]]ing quality, the gold solder alloy must match the fineness of the work, and alloy formulas are manufactured to color-match yellow and white gold. Gold solder is usually made in at least three melting-point ranges referred to as Easy, Medium and Hard. By using the hard, high-melting point solder first, followed by solders with progressively lower melting points, goldsmiths can assemble complex items with several separate soldered joints. Gold can also be made into [[gold thread|thread]] and used in [[embroidery]]. === Electronics === Only 10% of the world consumption of new gold produced goes to industry,<ref name="oil-price.com-worlds-gold-consumption 2011" /> but by far the most important industrial use for new gold is in fabrication of corrosion-free [[electrical connectors]] in computers and other electrical devices. For example, according to the World Gold Council, a typical cell phone may contain 50 mg of gold, worth about 2 dollars 82 cents. But since nearly one billion cell phones are produced each year, a gold value of US$2.82 in each phone adds to US$2.82 billion in gold from just this application.<ref>[http://www.usfunds.com/slideshows/the-many-uses-of-gold/ Uses of gold] {{Webarchive|url=https://archive.today/20141104233515/http://www.usfunds.com/slideshows/the-many-uses-of-gold/ |date=4 November 2014 }} Accessed 4 November 2014</ref> (Prices updated to November 2022) Though gold is attacked by free chlorine, its good conductivity and general resistance to oxidation and corrosion in other environments (including resistance to non-chlorinated acids) has led to its widespread industrial use in the electronic era as a thin-layer coating on [[electrical connector]]s, thereby ensuring good connection. For example, gold is used in the connectors of the more expensive electronics cables, such as audio, video and [[USB]] cables. The benefit of using gold over other connector metals such as [[tin]] in these applications has been debated; gold connectors are often criticized by audio-visual experts as unnecessary for most consumers and seen as simply a marketing ploy. However, the use of gold in other applications in electronic sliding contacts in highly humid or corrosive atmospheres, and in use for contacts with a very high failure cost (certain [[computer]]s, communications equipment, [[spacecraft]], [[jet aircraft]] engines) remains very common.<ref>{{cite book |editor-last=Krech III |editor-first=Shepard |editor2-last=Merchant |editor2-first=Carolyn |editor3-last=McNeill |editor3-first=John Robert |title=Encyclopedia of World Environmental History |volume=2: F–N |year=2004 |publisher=Routledge |isbn=978-0-415-93734-4 |pages=597– |url={{google books |plainurl=y |id=G7JrhAy5phoC |page=597}} }}</ref> Besides sliding electrical contacts, gold is also used in [[electrical contacts]] because of its resistance to [[corrosion]], [[electrical conductivity]], [[ductile|ductility]] and lack of [[toxicity]].<ref>{{cite web |title=General Electric Contact Materials |website=Electrical Contact Catalog (Material Catalog) |publisher=Tanaka Precious Metals |date=2005 |url=http://www.tanaka-precious.com/catalog/material.html|archive-url=https://web.archive.org/web/20010303213152/http://www.tanaka-precious.com/catalog/material.html|url-status=dead|archive-date=3 March 2001 |access-date=21 February 2007}}</ref> Switch contacts are generally subjected to more intense corrosion stress than are sliding contacts. Fine gold wires are used to connect [[semiconductor device]]s to their packages through a process known as [[wire bonding]]. The concentration of free electrons in gold metal is 5.91×10<sup>22</sup> cm<sup>−3</sup>.<ref>{{Cite book |url=https://books.google.com/books?id=MaWKDQAAQBAJ&pg=SA2-PA8 |title=Electronic, Magnetic, and Optical Materials, Second Edition |last1=Fulay |first1=Pradeep |last2=Lee |first2=Jung-Kun |date=2016 |publisher=CRC Press |isbn=978-1-4987-0173-0}}</ref> Gold is highly [[electrical conductivity|conductive]] to electricity and has been used for [[electrical wiring]] in some high-energy applications (only silver and copper are more conductive per volume, but gold has the advantage of corrosion resistance). For example, gold electrical wires were used during some of the [[Manhattan Project]]'s atomic experiments, but large high-current silver wires were used in the [[calutron]] isotope separator magnets in the project. It is estimated that 16% of the world's presently-accounted-for gold and 22% of the world's silver is contained in electronic technology in Japan.<ref>{{cite news |url=http://www.techradar.com/news/phone-and-communications/mobile-phones/japan-wants-citizens-to-donate-their-phone-to-make-2020-olympic-medals-1326938 |title=Japan wants citizens to donate their old phone to make 2020 Olympics medals |work=TechRadar |date=23 August 2016 |author=Peckham, James}}</ref> === Medicine === Metallic and gold compounds have long been used for medicinal purposes. Gold, usually as the metal, is perhaps the most anciently administered medicine (apparently by shamanic practitioners)<ref>{{cite journal |doi=10.1007/s10787-007-0021-x |title=Clinical pharmacology of gold |date=2008 |last1=Kean |first1=W. F. |last2=Kean |first2=I. R. L. |journal=Inflammopharmacology |volume=16 |issue=3 |pages=112–25 |pmid=18523733|s2cid=808858 }}</ref> and known to [[Dioscorides]].<ref>{{cite book |last1=Moir |first1=David Macbeth |url=https://archive.org/details/b21364047 |page=[https://archive.org/details/b21364047/page/225 225] |title=Outlines of the ancient history of medicine |publisher=William Blackwood |date=1831}}</ref><ref>Mortier, Tom. [https://lirias.kuleuven.be/bitstream/1979/254/2/thesis_finaal.pdf An experimental study on the preparation of gold nanoparticles and their properties] {{Webarchive|url=https://web.archive.org/web/20131005015930/https://lirias.kuleuven.be/bitstream/1979/254/2/thesis_finaal.pdf |date=5 October 2013 }}, PhD thesis, University of Leuven (May 2006)</ref> In medieval times, gold was often seen as beneficial for the health, in the belief that something so rare and beautiful could not be anything but healthy. Even some modern [[esotericism|esotericists]] and forms of [[alternative medicine]] assign metallic gold a healing power. In the 19th century gold had a reputation as an [[anxiolytic]], a therapy for nervous disorders. [[Depression (mood)|Depression]], [[epilepsy]], [[migraine]], and glandular problems such as [[amenorrhea]] and [[impotence]] were treated, and most notably [[alcoholism]] (Keeley, 1897).<ref>{{Cite journal |last1=Richards |first1=Douglas G. |last2=McMillin |first2=David L. |last3=Mein |first3=Eric A. |last4=Nelson |first4=Carl D. |name-list-style=amp |title=Gold and its relationship to neurological/glandular conditions |journal=The International Journal of Neuroscience |volume=112 |issue=1 |pages=31–53 |date=January 2002 |pmid=12152404 |doi=10.1080/00207450212018|s2cid=41188687 }}</ref> The apparent paradox of the actual toxicology of the substance suggests the possibility of serious gaps in the understanding of the action of gold in physiology.<ref>{{cite journal |doi=10.1006/biol.1997.0123 |pmid=9637749 |title=Gold, the Noble Metal and the Paradoxes of its Toxicology |date=1998 |last1=Merchant |first1=B. |journal=Biologicals |volume=26 |pages=49–59 |issue=1}}</ref> Only salts and radioisotopes of gold are of pharmacological value, since elemental (metallic) gold is inert to all chemicals it encounters inside the body (e.g., ingested gold cannot be attacked by stomach acid). Some gold salts do have [[anti-inflammatory]] properties and at present two are still used as pharmaceuticals in the treatment of arthritis and other similar conditions in the US ([[sodium aurothiomalate]] and [[auranofin]]). These drugs have been explored as a means to help to reduce the pain and swelling of [[rheumatoid arthritis]], and also (historically) against [[tuberculosis]] and some parasites.<ref name="Messorri">{{Cite book |first1=L. |last1=Messori |first2=G. |last2=Marcon |chapter-url=https://books.google.com/books?id=wgifUs8dFbgC&pg=PA279 |chapter=Gold Complexes in the treatment of Rheumatoid Arthritis |title=Metal ions and their complexes in medication |editor-last=Sigel |editor-first=Astrid |publisher=CRC Press |date=2004 |isbn=978-0-8247-5351-1 |pages=280–301}}</ref> Gold alloys are used in [[restorative dentistry]], especially in tooth restorations, such as [[crown (dentistry)|crowns]] and permanent [[bridge (dentistry)|bridges]]. The gold alloys' slight malleability facilitates the creation of a superior molar mating surface with other teeth and produces results that are generally more satisfactory than those produced by the creation of porcelain crowns. The use of gold crowns in more prominent teeth such as incisors is favored in some cultures and discouraged in others. [[Colloidal gold]] preparations (suspensions of [[gold nanoparticle]]s) in water are intensely red-[[color]]ed, and can be made with tightly controlled particle sizes up to a few tens of nanometers across by reduction of gold chloride with [[citrate]] or [[ascorbate]] ions. Colloidal gold is used in research applications in medicine, biology and [[materials science]]. The technique of [[immunogold labeling]] exploits the ability of the gold particles to adsorb protein molecules onto their surfaces. Colloidal gold particles coated with specific antibodies can be used as probes for the presence and position of antigens on the surfaces of cells.<ref>{{Cite journal |doi=10.1016/0019-2791(71)90496-4 |pmid=4110101 |date=1971 |last1=Faulk |first1=W. P. |last2=Taylor |first2=G. M. |title=An immunocolloid method for the electron microscope |volume=8 |issue=11 |pages=1081–3 |journal=Immunochemistry}}</ref> In ultrathin sections of tissues viewed by [[electron microscope|electron microscopy]], the immunogold labels appear as extremely dense round spots at the position of the [[antigen]].<ref>{{Cite journal |pmid=6153194 |date=1980 |last1=Roth |first1=J. |last2=Bendayan |first2=M. |last3=Orci |first3=L. |title=FITC-protein A-gold complex for light and electron microscopic immunocytochemistry |volume=28 |issue=1 |pages=55–7 |journal=Journal of Histochemistry and Cytochemistry |doi=10.1177/28.1.6153194 |doi-access=free}}</ref> Gold, or alloys of gold and [[palladium]], are applied as conductive coating to biological specimens and other non-conducting materials such as plastics and glass to be viewed in a [[scanning electron microscope]]. The coating, which is usually applied by [[sputtering]] with an [[argon]] [[plasma (physics)|plasma]], has a triple role in this application. Gold's very high electrical conductivity drains [[electric charge|electrical charge]] to earth, and its very high density provides stopping power for electrons in the [[electron beam]], helping to limit the depth to which the electron beam penetrates the specimen. This improves definition of the position and topography of the specimen surface and increases the [[Angular resolution|spatial resolution]] of the image. Gold also produces a high output of [[secondary emission|secondary electrons]] when irradiated by an electron beam, and these low-energy electrons are the most commonly used signal source used in the scanning electron microscope.<ref>{{Cite book |last1=Bozzola |first1=John J. |last2=Russell |first2=Lonnie Dee |url=https://books.google.com/books?id=RqSMzR-IXk0C&pg=PA65 |page=65 |title=Electron microscopy: principles and techniques for biologists |name-list-style=amp |publisher=Jones & Bartlett Learning |date=1999 |isbn=978-0-7637-0192-5}}</ref> The isotope [[gold-198]] ([[half-life]] 2.7 days) is used in [[nuclear medicine]], in some [[cancer]] treatments and for treating other diseases.<ref>{{cite web |url=http://web.missouri.edu/~kattik/katti/katres.html |archive-url=https://web.archive.org/web/20090314121232/http://web.missouri.edu/~kattik/katti/katres.html |archive-date=14 March 2009 |title=Nanoscience and Nanotechnology in Nanomedicine: Hybrid Nanoparticles In Imaging and Therapy of Prostate Cancer |publisher=Radiopharmaceutical Sciences Institute, University of Missouri-Columbia}}</ref><ref>{{cite journal |doi=10.1211/jpp.60.8.0005 |title=Radiotherapy enhancement with gold nanoparticles |date=2008 |last1=Hainfeld |first1=James F. |last2=Dilmanian |first2=F. Avraham |last3=Slatkin |first3=Daniel N. |last4=Smilowitz |first4=Henry M. |s2cid=32861131 |journal=Journal of Pharmacy and Pharmacology |volume=60 |issue=8 |pages=977–85 |pmid=18644191 }}</ref> === Cuisine === [[Image:Cake with pure gold (3038005040).jpg|thumb|Cake with gold decoration served at the [[Amstel Hotel]], [[Amsterdam]] ]] * Gold can be used in food and has the [[E number]] 175.<ref name="FSA">{{Cite news |url=http://www.food.gov.uk/safereating/chemsafe/additivesbranch/enumberlist |title=Current EU approved additives and their E Numbers |date=27 July 2007 |publisher=Food Standards Agency, UK}}</ref> In 2016, the [[European Food Safety Authority]] published an opinion on the re-evaluation of gold as a food additive. Concerns included the possible presence of minute amounts of gold [[nanoparticle]]s in the food additive, and that gold nanoparticles have been shown to be [[genotoxic]] in mammalian cells [[in vitro]].<ref>{{cite journal |title=Scientific Opinion on the re-evaluation of gold (E 175) as a food additive |journal=EFSA Journal |volume=14 |issue=1 |year=2016 |issn=1831-4732 |doi=10.2903/j.efsa.2016.4362 |page=4362|doi-access=free}}</ref> * [[Gold leaf]], flake or dust is used on and in some gourmet foods, notably sweets and drinks as decorative ingredient.<ref>{{cite web |title=The Food Dictionary: Varak |publisher=Barron's Educational Services, Inc. |date=1995 |url=http://www.epicurious.com/cooking/how_to/food_dictionary/entry?id=5061 |archive-url=https://web.archive.org/web/20060523014547/http://www.epicurious.com/cooking/how_to/food_dictionary/entry?id=5061 |archive-date=23 May 2006 |access-date=27 May 2007}}</ref> Gold flake was used by the nobility in [[medieval Europe]] as a decoration in food and drinks,<ref>{{Cite book |url=https://books.google.com/books?id=OMLuBQAAQBAJ&pg=PT94 |title=Commensality: From Everyday Food to Feast |last1=Kerner |first1=Susanne |last2=Chou |first2=Cynthia |last3=Warmind |first3=Morten |page=94 |date=2015 |publisher=Bloomsbury Publishing |isbn=978-0-85785-719-4}}</ref> * Danziger Goldwasser (German: Gold water of Danzig) or [[Goldwasser]] ({{lang-en|Goldwater}}) is a traditional German herbal [[liqueur]]<ref>{{Cite book |chapter-url=https://books.google.com/books?id=tsUNAAAAYAAJ&pg=PA101 |title=Deutschland nebst Theilen der angrenzenden Länder |chapter=Danzig |first=Karl |last=Baedeker |date=1865 |publisher=Karl Baedeker |language=de}}</ref> produced in what is today [[Gdańsk]], [[Poland]], and [[Schwabach]], Germany, and contains flakes of gold leaf. There are also some expensive (c. $1000) cocktails which contain flakes of gold leaf. However, since metallic gold is inert to all body chemistry, it has no taste, it provides no nutrition, and it leaves the body unaltered.<ref>{{cite web |url=http://geology.com/minerals/gold/uses-of-gold.shtml |title=The Many Uses of Gold |access-date=6 June 2009 |author=King, Hobart M. |publisher=geology.com}}</ref> * [[Vark]] is a [[Metal leaf|foil]] composed of a pure metal that is sometimes gold,<ref>[http://www.delafee.com/Edible+Gold+Creations_Information+on+edible+gold/ Gold in Gastronomy] {{Webarchive|url=https://web.archive.org/web/20160304002554/http://www.delafee.com/Edible+Gold+Creations_Information+on+edible+gold/ |date=4 March 2016 }}. deLafee, Switzerland (2008)</ref> and is used for [[Garnish (food)|garnishing]] sweets in South Asian cuisine. === Miscellanea === [[File:James Webb Space Telescope Mirror33.jpg|thumb|Mirror for the [[James Webb Space Telescope]] coated in gold to reflect infrared light]] [[File:Kamakshi Amman Temple with golden roof, Kanchipuram.jpg|thumb|Kamakshi Amman Temple with golden roof, [[Kanchipuram]].]] * Gold produces a deep, intense red color when used as a coloring agent in [[cranberry glass]]. * In photography, gold toners are used to shift the color of [[silver bromide]] black-and-white prints towards brown or blue tones, or to increase their stability. Used on [[sepia tone|sepia-toned]] prints, gold toners produce red tones. Kodak published formulas for several types of gold toners, which use gold as the chloride.<ref>[https://web.archive.org/web/20160817134815/http://www.kodak.com/global/en/professional/support/techPubs/g23/g23.pdf Toning black-and-white materials]. Kodak Technical Data/Reference sheet G-23, May 2006.</ref> * Gold is a good reflector of [[electromagnetic radiation]] such as [[infrared]] and [[visible spectrum|visible light]], as well as [[radio frequency|radio waves]]. It is used for the protective coatings on many artificial [[satellite]]s, in infrared protective faceplates in thermal-protection suits and astronauts' helmets, and in [[electronic warfare]] planes such as the [[EA-6B Prowler]]. * Gold is used as the reflective layer on some [[Gold CD|high-end CDs]]. * Automobiles may use gold for heat shielding. [[McLaren]] uses gold foil in the engine compartment of its [[McLaren F1|F1]] model.<ref>{{cite book |last1=Martin |first1=Keith |url=https://books.google.com/books?id=pUhMRLiHiY8C&pg=PA42 |title=1997 McLaren F1}}</ref> * Gold can be manufactured so thin that it appears semi-transparent. It is used in some aircraft cockpit windows for [[Deicing|de-icing]] or anti-icing by passing electricity through it. The heat produced by the resistance of the gold is enough to prevent ice from forming.<ref name="gbc215">{{Cite news |url=http://www.goldbulletin.org/assets/file/goldbulletin/downloads/Cooke_2_15.pdf |archive-url=https://web.archive.org/web/20110726122946/http://www.goldbulletin.org/assets/file/goldbulletin/downloads/Cooke_2_15.pdf |archive-date=26 July 2011 |title=The Demand for Gold by Industry |publisher=Gold bulletin |access-date=6 June 2009}}</ref> * Gold is attacked by and dissolves in alkaline solutions of potassium or sodium [[cyanide]], to form the salt gold cyanide—a technique that has been used in extracting metallic gold from ores in the [[cyanide process]]. Gold cyanide is the [[electrolyte]] used in commercial [[electroplating]] of gold onto base metals and [[electroforming]]. * Gold chloride ([[chloroauric acid]]) solutions are used to make colloidal gold by reduction with [[citrate]] or [[ascorbate]] [[ions]]. Gold chloride and gold oxide are used to make cranberry or red-colored glass, which, like [[colloid]]al gold suspensions, contains evenly sized spherical [[gold nanoparticle]]s.<ref>{{cite web |url=http://chemistry.about.com/cs/inorganic/a/aa032503a.htm |title=Colored glass chemistry |access-date=6 June 2009 |archive-date=13 February 2009 |archive-url=https://web.archive.org/web/20090213164051/http://chemistry.about.com/cs/inorganic/a/aa032503a.htm |url-status=dead }}</ref> * Gold, when dispersed in nanoparticles, can act as a [[Heterogeneous gold catalysis|heterogeneous catalyst]] of chemical reactions. * In recent years, gold has been used as a symbol of pride by the [[autism rights movement]], as its symbol Au could be seen as similar to the word "[[Autism spectrum disorder|autism]]".<ref>{{cite web |date=2 April 2021 |title=Why 'Going Gold' is important on Autism Acceptance Day. |url=https://edpsy.org.uk/blog/2021/why-going-gold-is-important-on-autism-acceptance-day-2nd-april/ |website=Edpsy}}</ref> == Toxicity == Pure metallic (elemental) gold is non-toxic and non-irritating when ingested<ref>{{cite web |last=Dierks |first=S. |title=Gold MSDS |url=http://www.espi-metals.com/msds's/gold.htm |archive-url=https://web.archive.org/web/20061110104358/http://www.espi-metals.com/msds%27s/gold.htm |url-status=dead |archive-date=10 November 2006 |publisher=Electronic Space Products International |date=May 2005 |access-date=21 December 2021 }}</ref> and is sometimes used as a food decoration in the form of [[gold leaf]].<ref>{{Cite book |url=https://books.google.com/books?id=4zK6CgAAQBAJ&pg=PA5 |title=Gold Nanoparticles for Physics, Chemistry and Biology |last1=Louis |first1=Catherine |last2=Pluchery |first2=Olivier |date=2012 |publisher=World Scientific |isbn=978-1-84816-807-7}}</ref> Metallic gold is also a component of the alcoholic drinks [[Goldschläger]], [[Gold Strike (drink)|Gold Strike]], and [[Goldwasser]]. Metallic gold is approved as a [[food additive]] in the EU ([[E number|E175]] in the [[Codex Alimentarius]]). Although the gold ion is toxic, the acceptance of metallic gold as a food additive is due to its relative chemical inertness, and resistance to being corroded or transformed into soluble salts (gold compounds) by any known chemical process which would be encountered in the human body. Soluble compounds ([[gold salts]]) such as [[gold(I,III) chloride|gold chloride]] are toxic to the liver and kidneys. Common [[cyanide]] salts of gold such as potassium gold cyanide, used in gold [[electroplating]], are toxic by virtue of both their cyanide and gold content. There are rare cases of lethal gold poisoning from [[potassium gold cyanide]].<ref>{{Cite journal |last1=Wright |first1=I. H. |first2=J. C. |last2=Vesey |date=1986 |title=Acute poisoning with gold cyanide |journal=Anaesthesia |volume=41 |issue=79 |pages=936–939 |doi=10.1111/j.1365-2044.1986.tb12920.x |pmid=3022615|s2cid=32434351 |doi-access=free }}</ref><ref>{{Cite journal |last1=Wu |first1=Ming-Ling |first2=Wei-Jen |last2=Tsai |first3=Jiin |last3=Ger |first4=Jou-Fang |last4=Deng |last5=Tsay |first5=Shyh-Haw |display-authors=5 |last6=Yang |first6=Mo-Hsiung |journal=Clinical Toxicology |date=2001 |volume=39 |issue=7 |pages=739–743 |title=Cholestatic Hepatitis Caused by Acute Gold Potassium Cyanide Poisoning |doi=10.1081/CLT-100108516 |pmid=11778673|s2cid=44722156 }}</ref> Gold toxicity can be ameliorated with [[chelation therapy]] with an agent such as [[dimercaprol]]. Gold metal was voted [[Allergen of the Year]] in 2001 by the American Contact Dermatitis Society; gold contact allergies affect mostly women.<ref name="TsurutaMatsunaga2001">{{cite journal |last1=Tsuruta |first1=Kyoko |last2=Matsunaga |first2=Kayoko |last3=Suzuki |first3=Kayoko |last4=Suzuki |first4=Rie |last5=Akita |first5=Hirotaka |last6=Washimi |first6=Yasuko |last7=Tomitaka |first7=Akiko |last8=Ueda |first8=Hiroshi |title=Female predominance of gold allergy |journal=Contact Dermatitis |volume=44 |issue=1 |year=2001 |pages=48–49 |doi=10.1034/j.1600-0536.2001.440107-22.x |pmid=11156030|s2cid=42268840 }}</ref> Despite this, gold is a relatively non-potent contact allergen, in comparison with metals like [[nickel]].<ref>{{Cite news |last=Brunk |first=Doug |url=http://www.highbeam.com/doc/1G1-176478357.html |archive-url=https://web.archive.org/web/20110624033428/http://www.highbeam.com/doc/1G1-176478357.html |url-status=dead |archive-date=24 June 2011 |title=Ubiquitous nickel wins skin contact allergy award for 2008 |date=15 February 2008}}</ref> A sample of the fungus ''[[Aspergillus niger]]'' was found growing from gold mining solution; and was found to contain cyano metal complexes, such as gold, silver, copper, iron and zinc. The fungus also plays a role in the solubilization of heavy metal sulfides.<ref>{{cite book |last=Singh |first=Harbhajan |url=https://books.google.com/books?id=WY3YvfNoouMC&pg=PA533 |title=Mycoremediation: Fungal Bioremediation |page=509 |isbn=978-0-470-05058-3 |date=2006|publisher=John Wiley & Sons }}</ref> == See also == [[File:Pyrit 01.jpg|thumb|right|Iron pyrite or "fool's gold"]] {{Colbegin|colwidth=20em}} * [[Bulk leach extractable gold]], for sampling ores * [[Chrysiasis]] (dermatological condition) * [[Digital gold currency]], form of electronic currency * [[GFMS]] business consultancy * [[Gold fingerprinting]], use impurities to identify an alloy * [[Gold standard]] in banking * [[List of countries by gold production]] * [[Tumbaga]], alloy of gold and copper * [[Iron pyrite]], fool's gold * [[Nordic gold]], non-gold copper alloy {{colend}}{{Clear}} == References == {{Reflist|30em}} ==Further reading== * Bachmann, H. G. ''The lure of gold : an artistic and cultural history'' (2006) [https://archive.org/details/lureofgold0000unse online] * Bernstein, Peter L. ''The Power of Gold: The History of an Obsession'' (2000) [https://archive.org/details/powerofgoldhisto00bern online] * Brands, H.W. ''The Age of Gold: The California Gold Rush and the New American Dream'' (2003) [https://www.amazon.com/Age-Gold-California-American-Recover/dp/0385720882/ excerpt] * Buranelli, Vincent. ''Gold : an illustrated history'' (1979) [https://archive.org/details/goldillustratedh00bura online]' wide-ranging popular history * Cassel, Gustav. "The restoration of the gold standard." ''Economica'' 9 (1923): 171–185. [https://www.jstor.org/stable/2548130 online] * Eichengreen, Barry. ''Golden Fetters: The Gold Standard and the Great Depression, 1919–1939'' (Oxford UP, 1992). * Ferguson, Niall. ''The Ascent of Money – Financial History of the World'' (2009) [https://archive.org/details/ascentofmoneyf00ferg online] * Hart, Matthew, [https://books.google.com/books?id=kSI5AAAAQBAJ Gold: The Race for the World's Most Seductive Metal] ''Gold : the race for the world's most seductive metal", New York: Simon & Schuster, 2013. {{ISBN|9781451650020}}'' * Johnson, Harry G. "The gold rush of 1968 in retrospect and prospect". ''American Economic Review'' 59.2 (1969): 344–348. [https://www.jstor.org/stable/1823687 online] * Kwarteng, Kwasi. ''War and Gold: A Five-Hundred-Year History of Empires, Adventures, and Debt'' (2014) [https://archive.org/details/wargoldfivehundr0000kwar online] * Vilar, Pierre. ''A History of Gold and Money, 1450–1920'' (1960). [https://archive.org/details/historyofgoldmon0000vila_c6t2 online] * Vilches, Elvira. ''New World Gold: Cultural Anxiety and Monetary Disorder in Early Modern Spain'' (2010). == External links == {{Wikiquote|Gold}} {{Commons|Gold}} {{Wiktionary|gold}} * {{cite EB1911|wstitle=Gold|volume=11|short=x}} * [https://web.archive.org/web/20080417110808/http://www.rsc.org/chemistryworld/podcast/element.asp Chemistry in its element podcast] (MP3) from the [[Royal Society of Chemistry]]'s [[Chemistry World]]: [http://www.rsc.org/images/CIIE_Gold_48k_tcm18-118269.mp3 Gold] www.rsc.org * [http://www.periodicvideos.com/videos/079.htm Gold] at ''[[The Periodic Table of Videos]]'' (University of Nottingham) * [https://web.archive.org/web/20080307000911/http://www.epa.gov/epaoswer/other/mining/techdocs/gold.pdf ''Getting Gold'' 1898 book], www.lateralscience.co.uk * {{webarchive |url=https://web.archive.org/web/20080307000911/http://www.epa.gov/epaoswer/other/mining/techdocs/gold.pdf |date=7 March 2008 |title=Technical Document on Extraction and Mining of Gold }}, www.epa.gov * [https://www.rsc.org/periodic-table/element/79/gold Gold element information] – rsc.org {{Periodic table (navbox)}} {{Gold compounds}} {{Jewellery}} {{Authority control}} [[Category:Gold| ]] [[Category:Chemical elements]] [[Category:Transition metals]] [[Category:Noble metals]] [[Category:Precious metals]] [[Category:Cubic minerals]] [[Category:Minerals in space group 225]] [[Category:Dental materials]] [[Category:Electrical conductors]] [[Category:Native element minerals]] [[Category:E-number additives]] [[Category:Symbols of Alaska]] [[Category:Symbols of California]] [[Category:Chemical elements with face-centered cubic structure]] [[Category:Coinage metals and alloys]] [[Category:Symbols of Victoria]] Summary: Please note that all contributions to Christianpedia may be edited, altered, or removed by other contributors. 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